Zobrazeno 1 - 10
of 66
pro vyhledávání: '"K. Sriramam"'
Publikováno v:
Reaction Kinetics and Catalysis Letters. 61:209-215
The reaction under study is first order in the complex ion over the entire composition range of the mixed solvent. A minimum amount of mineral acid is needed for completion of the reaction (formation of colorless products), but the rate is practicall
Publikováno v:
Transition Metal Chemistry. 18:231-237
The natural decay of Fe(phen) f3 p3+ , where no CeIV is employed for scavenging the side reaction product, Fe(phen) f3 p2+ , is now treated as a complex reaction involving two parallel processes, and the experimental kinetics are consistent with the
Publikováno v:
International Journal of Chemical Kinetics. 24:919-931
The kinetics of dissociation of tris-2,2′-bipyridyl-iron(II) complex ion have been examined in aqueous acetic acid solutions. The reaction is first order in the complex ion; the dependence of rate on H+ is somewhat like that observed in aqueous sol
Publikováno v:
Transition Metal Chemistry. 15:126-131
The kinetics of the iodine-catalysed reaction of vanadium(V) with arsenious acid in dilute H2SO4, leading to the formation of vanadium(IV) and arsenic acid, have been investigated spectrophotometrically. Plausible pathways consistent with the experim
Publikováno v:
Zeitschrift für Physikalische Chemie. :953-961
Publikováno v:
Mikrochimica Acta. 71:251-258
A new scheme for the detection of Ce(IV), Cr(VI) and V(V) in binary or ternary mixtures is reported. The procedure is based on the reaction of these species with acridone to give a rose-red oxidation product, combined with methods of selective reduct
Publikováno v:
Zeitschrift für Physikalische Chemie. 137:37-42
Publikováno v:
Mikrochimica Acta. 81:227-233
Hydrolysis of hexachloroantimonate(V), catalysed by iodide, has been used as a new indicator reaction for the determination of silver in microquantities by a kinetic procedure. The kinetics and mechanism of the indicator reaction have been elucidated
Publikováno v:
Mikrochimica Acta. 78:469-475
There is no need for a catalyst in the potentiometric or spectrophotometric titration of antimony(III) with chromium(VI). The failure of titrations using indicators is due to slowness of the oxidized indicator-Sb(III) reaction; the indicator reaction
Publikováno v:
Zeitschrift für Physikalische Chemie. :155-160