Zobrazeno 1 - 10
of 17
pro vyhledávání: '"K. Siepen"'
Publikováno v:
Applied Organometallic Chemistry. 14:549-556
Bimetallic Pt/Rh heterogeneous catalysts based on nanoscaled colloids supported on activated charcoal have been shown to exhibit maximum activity in hydrogenation of butyronitrile at a composition of 10 atom% Pt and 90 atom% Rh in the metallic core.
Publikováno v:
Journal of the American Chemical Society. 120:6019-6023
The reduction of [N(octyl)4]2[CuCl2Br2] in organic solution (toluene) using Li[BEt3H] leads to colloidal Cu protected by cationic surfactants (NR4+). According to HRTEM (high-resolution transmission electron microscopy) and UV/vis data, the organosol
Publikováno v:
Applied Organometallic Chemistry. 11:783-796
The performance of heterogeneous catalysts based on surfactant-stabilized palladium colloids is compared with conventional Pd/C and Lindlar catalysts in the partial hydrogenation of 3-hexyn-1-ol under optimized reaction conditions. The selectivity ca
Publikováno v:
Topics In Catalysis. 4:217-227
Preprepared nanometals stabilized by surfactants may be used as precursors for a new type of heterogeneous catalyst. Independent of the support these mono– or plurimetallic precursors may be optimized dependent on the size, composition, and structu
Autor:
Rainer Brinkmann, A. Schulze Tilling, Helmut Bönnemann, K. Siepen, Klaus Seevogel, Werner Brijoux, G. Braun
Publikováno v:
Journal of Organometallic Chemistry. 520:143-162
Solvent-stabilized organosols of the early transition metal series, e.g. Ti, Zr, Nb, and Mn, may be prepared by the reduction of the THF adducts or thioether solutions of the corresponding metal halides with K[BEt3H]. Mono- and bimetallic organosols
Publikováno v:
ChemInform. 29
Publikováno v:
Journal de Physique IV Proceedings
Journal de Physique IV Proceedings, EDP Sciences, 1997, 7 (C2), pp.C2-959-C2-960. ⟨10.1051/jp4:19972101⟩
Journal de Physique IV Proceedings, EDP Sciences, 1997, 7 (C2), pp.C2-959-C2-960. ⟨10.1051/jp4:19972101⟩
Innovative transition metal catalysts prepared on the basis of preformed colloidal nano-particles and stabilized by surfactants are of special interest with regard to industrial applications. The physical characterization of the metal colloid precurs
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f29724a3c8b899e6a2008e1e305b46ff
https://hal.archives-ouvertes.fr/jpa-00255158
https://hal.archives-ouvertes.fr/jpa-00255158
Autor:
J. Pollmann, J. Rothe, J. Richter, K. Siepen, Josef Hormes, Werner Brijoux, R. Franke, Helmut Bönnemann
Publikováno v:
Analytical and bioanalytical chemistry. 355(3-4)
Transition metal colloids are potential precursors of heterogeneous catalysts with application to selective chemical reactions. Sample preparation techniques are described. Experimental details are given of the characterization of these often air-sen
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Akademický článek
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