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pro vyhledávání: '"K. P. Kotyaev"'
Novel mechanism of methanol synthesis on conventional Cu-containing catalysts is proposed and proved. It includes a conjugation of methanol synthesis and WGSR and involves the transformations of strongly adsorbed species. The mechanism is based on th
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::e27b96c8db07a77f0134890099953d79
https://doi.org/10.1016/s0167-2991(00)81042-3
https://doi.org/10.1016/s0167-2991(00)81042-3
Autor:
A. Ya. Rozovskii, L. A. Vytnova, K. P. Kotyaev, Kh. M. Minachev, G. I. Lin, Yu. S. Khodakov, P. A. Makarov
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 33:255-259
1. Reduced and calcined SNM-1 catalyst adsorbs carbon monoxide in two forms: low-temperature (tmax 100°C) and high-temperature (tmax 550°C). The bonding strengths of these species and their concentration on the surface have been estimated. 2. Chemi
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 35:2430-2433
1. The strong chemisorption of the components of the reaction mixture in the methanol synthesis process on a SNM-1 catalyst has been determined by a thermal desorption method. There is no appreciable adsorption of CO and H2 on the reduced catalyst; w
Publikováno v:
Catalysis Letters. 3:299-307
Temperature-programmed reaction spectroscopic studies reveal two main transformation routes of methanol adsorbed on commercial Cu-containing catalysts. First the reverse methanol synthesis reaction (hydrolysis) CH3OH+H2O=CO3+3H2; a second route is no
Autor:
A. Ya. Rozovskii, G. I. Lin
Publikováno v:
Russian Chemical Bulletin; Nov2004, Vol. 53 Issue 11, p2455-2466, 12p
Publikováno v:
Russian Chemical Bulletin; Sep2002, Vol. 51 Issue 9, p1698-1701, 4p
Publikováno v:
Bulletin of the Academy of Sciences of The USSR, Division of Chemical Science; 1986, Vol. 35 Issue 12, p2433-2437, 5p
Publikováno v:
Bulletin of the Academy of Sciences of The USSR, Division of Chemical Science; 1986, Vol. 35 Issue 12, p2430-2433, 4p
Publikováno v:
Bulletin of the Academy of Sciences of The USSR, Division of Chemical Science; 1984, Vol. 33 Issue 2, p255-259, 5p
Publikováno v:
Bulletin of the Academy of Sciences of The USSR, Division of Chemical Science; 1984, Vol. 33 Issue 2, p251-255, 5p