Zobrazeno 1 - 10
of 19
pro vyhledávání: '"K. G. Ryabova"'
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 26:744-750
The complexes BF3-2CH3CH2COOH and BF3·2CH3COOH and the system 3BF3·2CH2ClCOOH-BF3·2CH3-COOH are active and stable catalysts of the carbonylation reaction (80–100°, pCO=100 atm) of tertiary and secondary alcohols of aliphatic and cyclic structur
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::6dcff5c4f9d8c8640a3a9079c9430f58
https://doi.org/10.1007/bf01108192
https://doi.org/10.1007/bf01108192
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 27:913-918
An equimolar mixture of a normal (or cyclic) alkene and an alkene with a branch at the double bond (or a tertiary alcohol) in the presence of the BF3·H2O -liquid-SO2 catalytic system under 1 atm of CO at a temperature of −30 to −40°C undergoes
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::c96deb0c5a48837bf20d9f43b69929b2
https://doi.org/10.1007/bf00928990
https://doi.org/10.1007/bf00928990
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 26:2165-2168
The carbonylation of olefins, with branching at the double bond, and of tertiary alcohols with CO at −30° and atmospheric pressure, in the presence of the catalyst system: BF3· H2O-liquid SO2, leads to the formation of mixtures of α,α-dialkylal
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::7efbdedeb5f9acf98fc67c611d06080c
https://doi.org/10.1007/bf00923644
https://doi.org/10.1007/bf00923644
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 25:1264-1267
BF3 Complexes with acetic or propionic acid are highly active and stable catalysts for the carbonylation of olefins and alcohols and may be used repeatedly without lowering the initial activity.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::43f8a2a68bec1375b0cdbee1349ca07a
https://doi.org/10.1007/bf00928065
https://doi.org/10.1007/bf00928065
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 28:784-790
1. The most active and selective catalysts for carbonylation of L-menthol, D,L-menthol, p-menthene, and 2,6-dimethyl-2,7-octadiene are BF3·2C2H5COOH, BF3·2CH3COOH, BF3·2CH2C1COOH, BF3·2CH2C1COOH, and BF3·2CH2C1COOH-BF3·2CH3COOH (3∶1). 2. The
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::b4e203735949e1346d440130dc6306d0
https://doi.org/10.1007/bf00923582
https://doi.org/10.1007/bf00923582
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 22:1760-1763
1. Cyclic glycol esters of trialkylcarbinylboric acids were synthesized from trialkylboranes and carbon monoxide in 60–70% yield, while tertiary alcohols were obtained by their oxidation. 2. The addition of small amounts of sodium metal changed the
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::f544c85a7c4719184ef97bc45de86af5
https://doi.org/10.1007/bf00932109
https://doi.org/10.1007/bf00932109
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 24:371-373
Olefins with branching at the double bond, and secondary and tertiary alcohols are carbonylated at atmospheric pressure and 25° in the presence of the catalyst system composed of the Cu(I)-CO and (BF3·H2O)·2(BF3·H3PO4) complexes to giveα,α-dime
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::cf90a4a9cef99239e5663afe0c1cec19
https://doi.org/10.1007/bf00925791
https://doi.org/10.1007/bf00925791
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 27:96-98
The 3BF3·2CH2C1COOH+BF3-2CH3COOH system effectively catalyzes the selective carbonylation of propylene and n-butylenes. At 95–105°C and a CO pressure of 200 atm, with an equimolar ratio catalyst∶olefin∶ water, propylene or mixed n-butylenes g
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::cb848ab81cd80ac363ce138ed2924ca1
https://doi.org/10.1007/bf01153217
https://doi.org/10.1007/bf01153217
Publikováno v:
Bulletin of the Academy of Sciences, USSR Division of Chemical Science. 15:1745-1747
1. The reactions of primary alkylmagnesium halides with carbon monoxide under pressure lead to the synthesis of olefins containing one carbon atom more than the doubled radical from the organomagnesium compound and with a double bond in the central p
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::651f69754134d8a8e26bf6bee1a64a90
https://doi.org/10.1007/bf00848716
https://doi.org/10.1007/bf00848716
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 21:1939-1941
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::0d780d3d2b637dee67855bbbfcc56799
https://doi.org/10.1007/bf00854610
https://doi.org/10.1007/bf00854610