Zobrazeno 1 - 10
of 16
pro vyhledávání: '"K. C. Santhosh"'
Publikováno v:
The Journal of Organic Chemistry. 64:8868-8872
Treatment of phosphites (P(OR)(3)) and MeO(2)CCCCO(2)Me with C(60) affords the corresponding fullerene derivatives (1, R = Me; 2, R = Et; 3, R = n-Bu) consisting of a phosphite ylide group and a cyclopropane ring on the fullerene moiety in high yield
Publikováno v:
The Journal of Organic Chemistry. 64:6664-6669
A unique method to introduce phosphorus substituents onto C(60) is based on the reaction of phosphines with acetylenes and C(60). Treatment of C(60) with phosphines (PR(3)) and electron-deficient acetylenes (A) in toluene at ambient temperature gave
Publikováno v:
Journal of the American Chemical Society. 120:12232-12236
A novel method for the construction of a fused cyclohexadiene ring on C60 based on a nickel-promoted [2+2+2] cycloaddition of 1,6-diynes is described. Treatment of C60 with terminal 1,6-diynes (HC⋮CCH2)2X) in the presence of NiCl2(PPh3)2, Zn, and P
Publikováno v:
The Journal of Organic Chemistry. 63:2699-2704
An alpha-carbonyl radical cyclization approach toward synthesis of angular triquinanes is described. As a model study, conjugate addition of 4-(trimethylsilyl)-3-butynylmagnesium chloride to enone 7 followed by trapping of the enolate with chlorotrim
Autor:
K. K. Balasubramanian, K. C. Santhosh
Publikováno v:
Synthetic Communications. 24:1049-1056
A straightforward, high yielding and stereoselective synthesis of 3,4-dihydro-4-aryloxy-3-bromo-2H-1-benzopyrans, compounds 8 and 9 by Mitsunobu coupling of the corresponding bromohydrins is reported.
Autor:
K. C. Santhosh, K. K. Balasubramanian
Publikováno v:
ChemInform. 23
Phenylation of 3-phenylsulfonlylchroman-4-ones using Ph3BiCO3leading to the synthesis of isoflavanones and isoflavones is reported.
Publikováno v:
ChemInform. 23
A simple and high yielding route to 3-alkylchromanones and 3-alkylchromones has been achieved from 3-alkyl-3-phenyl-sulphonyl-4-chromanones. A simple and high yielding route to 3-alkylchromanones and 3-alkylchromones has been achieved from 3-alkyl, 3
Autor:
K. K. Balasubramanian, K. C. Santhosh
Publikováno v:
ChemInform. 25
Publikováno v:
ChemInform. 29