Dithiolate and Catecholate Binding of Copper by the OO∼SS Bifunctional Ligand: Regioselectivity and Regioisomeric Transformations

Autor: K. A. Martyanov, Anna V. Cherkasova, Anton V. Cherkasov, Vladimir K. Cherkasov, Andrey G. Starikov, Viacheslav Kuropatov

Publikováno v: European Journal of Inorganic Chemistry. 2021:3292-3300

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::7a5cdb1415516d22499ba7dfb09966eb
https://doi.org/10.1002/ejic.202100517

3,6-Di-tert-Butyl-2-Hydroxy-4-Pyridinylphenolate and Tin(IV) Complexes it Forms: Synthesis and Structure Details and Solvatochromic Effect

Autor: K. A. Martyanov, Kira I. Pashanova, K. V. Arsen’eva, Alexandr V. Piskunov, Anton V. Cherkasov

Publikováno v: Russian Journal of Coordination Chemistry. 46:795-804

Two synthetic approaches were developed for the preparation of 3,6-di-tert-butyl-2-hydroxy-4-pyridinylphenolate (LH), a new zwitter-ionic redox-active diolate type ligand. Two heteroligand five-coordinate tin(IV) derivatives were prepared with this l

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::481485979c968db2ea93ef6707f3d990
https://doi.org/10.1134/s1070328420120064

Field-induced single-molecule magnets of dysprosium involving quinone derivatives

Autor: Bertrand Lefeuvre, Fabrice Pointillart, Vladimir K. Cherkasov, Vincent Dorcet, Jessica Flores Gonzalez, Sergey Norkov, Olivier Cador, K. A. Martyanov, Viacheslav Kuropatov

Publikováno v: Magnetochemistry
Magnetochemistry, MDPI, 2021, 7 (2), pp.1-13. ⟨10.3390/magnetochemistry7020024⟩
Volume 7
Issue 2
Magnetochemistry, Vol 7, Iss 24, p 24 (2021)
Magnetochemistry, 2021, 7 (2), pp.1-13. ⟨10.3390/magnetochemistry7020024⟩

The coordination reaction of the [Dy(hfac)3(H2O)2] units (hfac− = 1,1,1,5,5,5-hexafluoroacetylacetonate) with the two quinone-based derivatives 4,7-di-tert-butyl-2-(3,5-di-tert-butyl-4-oxocyclohexa-2,5-dien-1-ylidene)benzo[d][1,3]dithiole-5,6-dione

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b0e76ac4516e599f62b8e37a438e119f
https://hal.archives-ouvertes.fr/hal-03158005/document

Metallocomplexes, exhibiting catecholate binding mode for o-quinone, annulated with dithiete cycle

Autor: R.V. Rumyantcev, K. A. Martyanov, Vladimir K. Cherkasov, V.A. Kuropatov

Publikováno v: Inorganica Chimica Acta. 528:120604

Novel catecholate complexes (ditCat)SbPh3 (1), (ditCat)Ni(2,2′-bpy) (2) and (3,6-tBu-ditCat)VCp2 (3), containing annulated dithiete cycle, were synthesized by reactions of bifunctional o-quinone, annulated with dithiete ring (ditQ) with SbPh3, (2,2

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::2b948aba94b787a82034377f08b5f675
https://doi.org/10.1016/j.ica.2021.120604

New sterically-hindered o-quinones annelated with metal-dithiolates: regiospecificity in oxidative addition reactions of a bifacial ligand to the Pd and Pt complexes

Autor: Vera V. Khrizanforova, M. A. Samsonov, Vladimir K. Cherkasov, K. A. Martyanov, Yu. H. Budnikova, V. A. Kuropatov, Gleb A. Abakumov

Publikováno v: Dalton transactions (Cambridge, England : 2003). 45(17)

An unusual reactivity of sterically hindered o-quinones with an annelated dithiete ring towards coordination at a dithiolene site has been discovered. New Pd and Pt dithiolate complexes have been synthesized. The reaction proceeds regioselectively, a

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d55a243be2635a42266f7cd375dfae8b
https://pubmed.ncbi.nlm.nih.gov/27040038