Zobrazeno 1 - 10
of 606
pro vyhledávání: '"K. U. Ingold"'
Autor:
Bernard Meunier, Gary Brudvig, Jennifer L Mclain, Shun-ichi Murahashi, V L Pecoraro, D Riley, Anne Robert, J A Rodriguez, R A Sheldon, J S Valentine, C Young, James M Mayer, Julian Limburg, Jinbo Lee, Diane Cabelli, R H Crabtree, Sergiu M Gorun, John T Groves, Zhengbo Hu, K U Ingold, Kenneth D Karlin, Naruyoshi Komiya, Marie-aude Kopf, Hans Jorg Krueger, H Zhu
Since the classic work Metal-Catalyzed Oxidations of Organic Compounds (edited by R A Sheldon and J K Kochi, 1991), no book has been devoted to advances in the field of biomimetic oxidations, which was created nearly 18 years ago. This expanding rese
Publikováno v:
The Journal of organic chemistry. 61(6)
Laser flash photolysis has been used to determine the absolute rate constants for addition of several partially fluorinated n-alkyl radicals to three styrenes at 25 °C in Freon 113. Fluorination at the γ-position (RCF
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::c1a6d93fe244403a5f30d965ca0f014a
https://pubmed.ncbi.nlm.nih.gov/28616983
https://pubmed.ncbi.nlm.nih.gov/28616983
Publikováno v:
The Journal of Organic Chemistry. 72:8095-8098
Spectroscopic data are consistent with computations that show that, in their most stable conformations, the peroxyl moiety is equatorial in cyclohexylperoxyl radicals and axial in oxa- and most polyoxacyclohexyl-2-peroxyl radicals.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::796efd4d1ec985dcb0fa7ce5ad616de5
https://doi.org/10.1021/jo7014592
https://doi.org/10.1021/jo7014592
Autor:
K. U. Ingold, Merete Folmer Nielsen
Publikováno v:
Journal of the American Chemical Society. 128:1172-1182
Bimolecular rate constants for proton transfer from six phenols to the anthracene radical anion have been determined in up to eight solvents using electrochemical techniques. Effects of hydrogen bonding on measured rate constants were explored over a
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::244a40393ae667ce03e731ced99aa414
https://doi.org/10.1021/ja0548081
https://doi.org/10.1021/ja0548081
Autor:
Grzegorz Litwinienko, K. U. Ingold
Publikováno v:
The Journal of Organic Chemistry. 70:8982-8990
[reaction: see text] A prolonged search involving several dozen phenols, each in numerous solvents, for an ArOH/2,2-diphenyl-1-picrylhydrazyl (dpph(*)) reaction that is first-order in ArOH but zero-order in dpph(*) has reached a successful conclusion
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::23d3f4eefc86ada5a35a6c906aec3f07
https://doi.org/10.1021/jo051474p
https://doi.org/10.1021/jo051474p
Autor:
K. U. Ingold, Grzegorz Litwinienko
Publikováno v:
The Journal of Organic Chemistry. 69:5888-5896
The rates of reaction of 1,1-diphenyl-2-picrylhydrazyl (dpph*) radicals with curcumin (CU, 1,7-bis(4-hydroxy-3-methoxyphenyl)-1,6-heptadiene-3,5-dione), dehydrozingerone (DHZ, "half-curcumin"), and isoeugenol (IE) have been measured in methanol and e
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7105c7eddb3b03c78dc7f5cbf6c784c2
https://doi.org/10.1021/jo049254j
https://doi.org/10.1021/jo049254j
Publikováno v:
Accounts of Chemical Research. 37:334-340
The Hammett equation correlates the effects of Y on many different chemical properties of YC(6)H(4)ZX families of compounds. One of the most surprising is that the Z-X bond dissociation enthalpy (BDE), a homolytic property, can be correlated for some
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::94cb63e91557e21d1a195c9fcd844a1a
https://doi.org/10.1021/ar010010k
https://doi.org/10.1021/ar010010k
Autor:
K. U. Ingold
Publikováno v:
The Foundations of Physical Organic Chemistry: Fifty Years of the James Flack Norris Award ISBN: 9780841230712
The Foundations of Physical Organic Chemistry: Fifty Years of the James Flack Norris Award
The Foundations of Physical Organic Chemistry: Fifty Years of the James Flack Norris Award
In this Chapter the reader is conducted on a gentle cruise through the green and pleasant land of mechanistic radical chemistry. My love of chemistry arrived with a bang (potassium metal + water) and I was already enamored by “how fast?”. These t
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8eaae67385ab740d1e9415bddf5b93ed
https://doi.org/10.1021/bk-2015-1209.ch010
https://doi.org/10.1021/bk-2015-1209.ch010
Publikováno v:
The Journal of Physical Chemistry A. 106:11719-11725
Density functional theory indicates that the minimum energy structure of the diphenylaminyl radical, Ph2N, has a "staggered" conformation in which the two phenyl rings are twisted relative to each other by an angle, φ, of 40. In this conformation, t
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::924485295fcc49bbb54c9516054f1797
https://doi.org/10.1021/jp026279i
https://doi.org/10.1021/jp026279i