Výsledky vyhledávání - "K G, Caulton"

Autor: R. Miftakhov, N. Vedernikov, B. N. Solomonov, K. G. Caulton, S. V. Borisoglebski

Publikováno v: Chemistry of Heterocyclic Compounds. 38:406-416

Condensation of 2-pyridylmethyllithium or (6-methyl-2-pyridyl)methyllithium nucleophiles and pyridine, 2-picoline, or 4-tert-butylpyridine as electrophiles leads to new polydentate N-donor ligands, methyl-, tert-butyl-substituted tripyridinedimethane

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::7fc2938e76acd0b8d488fdc5cd50cef9
https://doi.org/10.1023/a:1016023103898

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Condensation of 2-Pyridylmethyllithium Nucleophiles and Pyridine Electrophiles as a Convenient Synthetic Route to Polydentate Chelating N-Donor Ligands

Autor: S. V. Borisoglebski, N. Vedernikov, K. G. Caulton, R. Miftakhov, B. N. Solomonov

Publikováno v: ChemInform. 34

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::77ca29e072f46656f18aba91f75c3e16
https://doi.org/10.1002/chin.200302117

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Effect of Lewis acidity on the synthesis of RuHCl(CO)(phosphine)(2): subtle influence of steric and electronic effects among P(i)Pr(3), P(i)Pr(2)(3,5-(CF(3))(2)C(6)H(3)), and P(i)Pr(2)Me

Autor: A V, Marchenko, J C, Huffman, P, Valerga, M J, Tenorio, M C, Puerta, K G, Caulton

Publikováno v: Inorganic chemistry. 40(25)

To evaluate the influence of steric, electronic, and synthetic factors, the synthesis of RuHCl(CO)[P(i)Pr(2)(3,5-(CF(3))(2)C(6)H(3))](2) was carried out, and its Lewis acidity toward Cl- was compared to that of RuHCl(CO)(P(i)Pr(3))(2). In this synthe

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::22634587647f95fb05611442db8b261e
https://pubmed.ncbi.nlm.nih.gov/11720500

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Unsaturated Ru(0) species with a constrained bis-phosphine ligand: [Ru(CO)2(tBu2PCH2CH2PtBu2)]2. Comparison to [Ru(CO)2(PtBu2Me)2]

Autor: T, Gottschalk-Gaudig, J C, Huffman, H, Gérard, O, Eisenstein, K G, Caulton

Publikováno v: Inorganic chemistry. 39(18)

The synthesis of Ru(C2H4)(CO)2(dtbpe) (dtbpe = tBu2PC2H4PtBu2), then green [Ru(CO)2(dtbpe)]n is described. In solution, n = 1, while in the solid state, n = 2; the dimer has two carbonyl bridges. DFTPW91, MP2, and CCSD(T) calculations show that the p

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::49c148cb23a166982f301323f95763e9
https://pubmed.ncbi.nlm.nih.gov/11198847

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Modification of the reactivity of polyhydrides with Lewis acids. Synthesis and reactivity of {IrH5[P(iso-C3H7)3]2}2Cu(CF3SO3). X-ray crystal structure of {IrH2(MeCN)2[P(iso-C3H7)3]2}(BF4)

Autor: K. G. Caulton, X. D. He, B. Chaudret, K. Folting, J. Fernandez-Baeza

Publikováno v: Inorganic Chemistry. 29:5000-5002

The reaction of IrH 5 (P i Pr 3 ) 2 (1) with [Cu(MeCN) 4 ]BF 4 (2:1) in acetone yields [IrH 2 (MeCN) 2 (P i Pr 3 ) 2 ]BF 4 , characterized by spectroscopic methods and X-ray diffraction, in 46% yield. A similar reaction with CuCF 3 SO 3 in CH 2 Cl 2

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::ce18682c8be8d1015bcf99958c539ccf
https://doi.org/10.1021/ic00349a033

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