Zobrazeno 1 - 6
of 6
pro vyhledávání: '"Jun Musashi"'
Publikováno v:
Synthesis. 2011:3615-3626
Aryl(chloro)methyl 4-tolyl sulfoxides were synthesized from arylmethyl 4-tolyl sulfoxides in moderate-to-good yields by sequential treatment with lithium diisopropylamide and tosyl chloride at low temperatures. Treatment of the lithium α-sulfinyl ca
Publikováno v:
Tetrahedron Letters. 48:7295-7300
Addition reaction of 1-chlorovinyl p -tolyl sulfoxides, which were derived from various aldehydes, with lithium enolate of tert -butyl acetate at −78 °C in THF gave adducts in high yields. Magnesium carbenoids were generated by treatment of these
Publikováno v:
Tetrahedron. 60:5453-5460
Treatment of 1-chloroalkyl phenyl sulfoxides with a Grignard reagent at low temperature gave magnesium carbenoids in quantitative yields. The generated magnesium carbenoids were found to be stable at lower than −60 °C for long periods of time and
Publikováno v:
ChemInform. 43
The reaction of the title compounds, prepared from the corresponding arylmethyl 4-tolyl sulfoxides, with carbonyl compounds in the presence of LDA affords functionalized chloro alcohols in good yields.
Publikováno v:
ChemInform. 39
Addition reaction of 1-chlorovinyl p -tolyl sulfoxides, which were derived from various aldehydes, with lithium enolate of tert -butyl acetate at −78 °C in THF gave adducts in high yields. Magnesium carbenoids were generated by treatment of these
Publikováno v:
ChemInform. 36
Treatment of 1-chloroalkyl phenyl sulfoxides having a geminal methyl group or a geminal benzyl group at the 2-position in THF at −78 °C with isopropylmagnesium chloride gave magnesium carbenoids. Carbenoid 1,3-CH insertion reaction of the magnesiu