Zobrazeno 1 - 6
of 6
pro vyhledávání: '"Julio C. Hernández-Ortiz"'
Autor:
Paul H. M. Van Steenberge, Ondrej Sedlacek, Julio C. Hernández-Ortiz, Bart Verbraeken, Marie-Françoise Reyniers, Richard Hoogenboom, Dagmar R. D’hooge
Publikováno v:
Nature Communications, Vol 10, Iss 1, Pp 1-14 (2019)
Understanding the functional group distribution in a polymer chain has been difficult, but this information can be very useful. Here the authors visualize the monomer distribution in individual polymer chains by combining experimental and theoretical
Externí odkaz:
https://doaj.org/article/27ebc420f09e4226a2487429da9fdcde
Autor:
Guy Marin, Dagmar R. D'hooge, Ana Luisa Vaz, Paul Van Steenberge, Klaas Remerie, Julio C. Hernández-Ortiz, Carolina Toloza, Fons Schreurs, Jan Nicolaas Eddy Duchateau, Marie-Françoise Reyniers
Publikováno v:
AIChE Journal. 63:4944-4961
For post-polymerization modification, a novel kinetic Monte Carlo (kMC) modeling strategy for the description of the reaction event history and the evolution of the microstructure of individual macrospecies with a complex topology is presented. The k
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::465cdc592d34c2d055f0891d5bae6eea
https://doi.org/10.1002/aic.15842
https://doi.org/10.1002/aic.15842
Autor:
Guy Marin, Dagmar R. D'hooge, Marie-Françoise Reyniers, Carolina Toloza, Julio C. Hernández-Ortiz, Fons Schreurs, Paul Van Steenberge, Jan Nicolaas Eddy Duchateau
Publikováno v:
Chemical Engineering Journal. 377:119980
Free radical induced grafting (FRIG) of polyolefins is described at industrially relevant time scales at which phase segregation occurs, leading to the formation of a monomer- and polyolefin-rich phase. The mass transfer of oligomeric species is acco
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::6674a5e9b8a0d9b86bf6d307e8508553
https://doi.org/10.1016/j.cej.2018.09.141
https://doi.org/10.1016/j.cej.2018.09.141
Autor:
Fons Schreurs, Guy Marin, Jan Nicolaas Eddy Duchateau, Carolina Toloza, Julio C. Hernández-Ortiz, Marie-Françoise Reyniers, Paul Van Steenberge, Dagmar R. D'hooge
Publikováno v:
Macromolecular Theory and Simulations. 28:1900035
For industrial-scale continuous free radical induced grafting of polyethylene, which involves the contact of a monomer- and polymer-rich phase, it is demonstrated that the functionalization selectivity and grafting density can be significantly improv
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::860f4ace0a47d22ea1cc4c86806469d8
https://doi.org/10.1002/mats.201900035
https://doi.org/10.1002/mats.201900035
Autor:
Marie-Françoise Reyniers, Guy Marin, Fons Schreurs, Carolina Toloza, Paul Van Steenberge, Jan Nicolaas Eddy Duchateau, Dagmar R. D'hooge, Julio C. Hernández-Ortiz
Publikováno v:
Macromolecular Theory and Simulations. 27:1800036
Radical‐induced grafting of polyethylene involves many reactions such as initiator dissociation, hydrogen abstraction, graft chain initiation, graft (de)propagation, crosslinking, and homo(de)polymerization. To ensure a successful grafting, both th
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::d54e8e1537e9ae1b40b7dc3b64263d3d
https://doi.org/10.1002/mats.201800036
https://doi.org/10.1002/mats.201800036
Publikováno v:
Macromolecular Theory and Simulations. 27:1700064
A kinetic model for the reversible addition-fragmentation chain transfer radical copolymerization of vinyl/divinyl monomers in supercritical carbon dioxide, using a multifunctional approach for polymer network formation, is presented. The process is
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::1b849ab5ea9882a64ec944d6f65b8eb9
https://doi.org/10.1002/mats.201700064
https://doi.org/10.1002/mats.201700064