Zobrazeno 1 - 10
of 19
pro vyhledávání: '"Julien Bonnamour"'
Autor:
Seok Hwan Kim, Isabelle Thome, Duanteng Chen, Astrid Beyer, Julien Bonnamour, Carsten Bolm, Sukbok Chang, Yu Yuan, Erik Zuidema
Publikováno v:
Advanced Synthesis & Catalysis. 352:2892-2898
Potassium hydroxide (KOH) in dimethyl sulfoxide (DMSO) forms a superbasic medium that allows one to access cross-coupling products from reactions between aryl halides with various sulfur-, oxygen- and nitrogen-based nucleophiles under transition meta
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::6b0d3b33adb7a5874733e7a73985d42e
https://doi.org/10.1002/adsc.201000575
https://doi.org/10.1002/adsc.201000575
Publikováno v:
Advanced Synthesis & Catalysis. 352:1577-1581
Intramolecular C-O bond forming reactions of aryl 2-bromobenzyl ketones lead to benzo[b]furans. The cyclizations can be catalyzed by 10 mol% of iron trichloride (of 98% or of 99.995% purity) or sub-mol% quantities of copper(II) chloride (of 99.995% p
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::96d1c6d06f83bbab6b2a1908223b71a1
https://doi.org/10.1002/adsc.201000269
https://doi.org/10.1002/adsc.201000269
Autor:
Jean Martinez, Thomas-Xavier Métro, Frédéric Lamaty, Julien Bonnamour, Anthony Duprez, Thomas Reidon, Jordi Sarpoulet
Publikováno v:
ChemInform. 47
It is shown that the complete elimination of organic solvents for the synthesis, purification, and isolation of the products resulting from acylation reactions of amines and other nucleophiles is possible.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::ae1c05fe3196c3019f69c151b758e9b2
https://doi.org/10.1002/chin.201602064
https://doi.org/10.1002/chin.201602064
Autor:
Thomas Reidon, Thomas-Xavier Métro, Jean Martinez, Frédéric Lamaty, Anthony Duprez, Julien Bonnamour, Jordi Sarpoulet
Publikováno v:
Chemistry-A European Journal
Chemistry-A European Journal, Wiley-VCH Verlag, 2015, 21 (36), pp.12787-12796. ⟨10.1002/chem.201501325⟩
Chemistry-A European Journal, Wiley-VCH Verlag, 2015, 21 (36), pp.12787-12796. ⟨10.1002/chem.201501325⟩
International audience; Acylation reactions are ubiquitous in the synthesis of natural products and biologically active compounds. Unfortunately,t hese reactions often require the use of large quantities of volatile and/or toxic solvents, either for
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::82e1dd976de43ff8e67b80913a83c669
https://hal.archives-ouvertes.fr/hal-02364122/file/Hal-99.pdf
https://hal.archives-ouvertes.fr/hal-02364122/file/Hal-99.pdf
Autor:
Julien Bonnamour, Carsten Bolm
Publikováno v:
Chemistry - A European Journal. 15:4543-4545
Clicking iron: Cheap and environmentally friendly [Fe(OAc)(2)] is used for the catalysis of cycloadditions between aryl nitriles and trimethylsilyl azide to prepare substituted 1H-tetrazoles in good yield (see scheme).
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::845e39fc678980171d8ae93cb1ae9efc
https://doi.org/10.1002/chem.200900169
https://doi.org/10.1002/chem.200900169
Autor:
Julien Bonnamour, Carsten Bolm
Publikováno v:
Organic Letters. 10:2665-2667
A practical iron-catalyzed intramolecular O-arylation reaction and its application in the synthesis of benzoxazole derivatives, starting from the readily available 2-haloanilines, is presented. The key cyclization step involves the use of a combinati
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0e828ddb810d9cbb1eb9e27fa229e753
https://doi.org/10.1021/ol800744y
https://doi.org/10.1021/ol800744y
Publikováno v:
Tetrahedron Letters. 48:8360-8362
gem -Chloroamine CF 3 CH(Cl)NHAc 1 reacts in a one-pot sequence with NaN 3 to afford trifluoromethyl azido compound 2 and further undergoes a Huisgen 1,3-dipolar cycloaddition with alkynes to yield 1,4-disubstitued 1,2,3-triazoles. The reaction is ca
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::8c9ff9a4c661faf77c2170d7f286d759
https://doi.org/10.1016/j.tetlet.2007.09.118
https://doi.org/10.1016/j.tetlet.2007.09.118
Autor:
Jean Martinez, Thomas Reidon, Thomas-Xavier Métro, Frédéric Lamaty, Julien Bonnamour, Jordi Sarpoulet
Publikováno v:
ChemInform. 44
A fast and efficient mechanochemical approach for the synthesis of carboxylic amides in the total absence of any organic solvent is realized and successfully applied to the preparation of the active pharmaceutical ingredient teriflunomide (IX).
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::b9d004aca419908ddf354eae3c0186bc
https://doi.org/10.1002/chin.201313031
https://doi.org/10.1002/chin.201313031
Mechanosynthesis of amides in the total absence of organic solvent from reaction to product recovery
Autor:
Thomas Reidon, Jean Martinez, Frédéric Lamaty, Julien Bonnamour, Jordi Sarpoulet, Thomas-Xavier Métro
Publikováno v:
Chemical Communications
Chemical Communications, Royal Society of Chemistry, 2012, 48 (96), pp.11781-11783. ⟨10.1039/c2cc36352f⟩
Chemical Communications, Royal Society of Chemistry, 2012, 48 (96), pp.11781-11783. ⟨10.1039/c2cc36352f⟩
International audience; The synthesis of various amides has been realised avoiding the use of any organic solvent from activation of carboxylic acids with CDI to isolation of the amides. Mechanochemistry was the key point of the process allowing rapi
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::80fec5be6d036578c354bef476d5f18f
https://pubmed.ncbi.nlm.nih.gov/23108313
https://pubmed.ncbi.nlm.nih.gov/23108313
Autor:
Carsten Bolm, Julien Bonnamour
Publikováno v:
ChemInform. 42
The catalyst is highly efficient for the preparation of the biologically important indole skeleton and the products are generally formed in good to excellent yields.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::e6c1344770b23ec199a205507b694c40
https://doi.org/10.1002/chin.201130114
https://doi.org/10.1002/chin.201130114