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Publikováno v:
Organometallics. 36:4477-4489
The reactivity of tridentate bis-aryloxy N-heterocyclic carbene (NHC) titanium complexes ([κ3-O,C,O]-NHC)Ti(X1)(X2) (X1 = X2 = Cl (1); X1 = X2 = OiPr (2)) via salt metathesis (with LiOBn, NaOAc), protonolysis (with (tBuO)3SiOH), and σ-bond metathes
Autor:
Erwan Le Roux, Vidar R. Jensen, Julie Hessevik, Ralte Lalrempuia, Karl W. Törnroos, Hajar Nsiri
Publikováno v:
Dalton Transactions. 45:14734-14744
Titanium(IV) complexes bearing an unsubstituted tridentate bis(phenolate) N-heterocyclic carbene (NHC) were synthesized and structurally identified. While sterically unencumbered NHC–Ti(IV) complexes bearing chloro and alkoxy co-ligands tend to dim