Zobrazeno 1 - 8
of 8
pro vyhledávání: '"Julie E, Niklas"'
Publikováno v:
Inorganic Chemistry. 62:2304-2316
Autor:
Luis M. Aguirre Quintana, Thayalan Rajeshkumar, Ningxin Jiang, Julie E. Niklas, John Bacsa, Laurent Maron, Henry S. La Pierre
Publikováno v:
Chemical Communications
Chemical Communications, 2022, 58 (95), pp.13242-13245. ⟨10.1039/d2cc05066h⟩
Chemical Communications, 2022, 58 (95), pp.13242-13245. ⟨10.1039/d2cc05066h⟩
Herein we report the first example of a mononuclear uranium complex, [U4+(NP(pip)3)4] (1-U), that selectively reduces dioxygen to produce a terminal oxo complex, [U6+O(NP(pip)3)4] (2-U; [NP(pip)3]1− is tris(piperidinyl)imidophosphorane). Reactions
Autor:
Julie E. Niklas, Henry S. La Pierre
Publikováno v:
Nature. 599:379-380
The scarcity and high radioactivity of the heaviest actinide elements, such as californium, make their study a formidable challenge. A landmark report describes the first structural characterization of a californium—carbon bond. The crystal structu
Publikováno v:
Inorganic chemistry. 59(14)
Derivatives of a novel pyrrole-containing Schiff base ligand system (called "pyrrophen") are presented which feature substituted phenylene linkers (R
Publikováno v:
Inorganica Chimica Acta. 529:120653
Regioisomerism about a phenyl spacer alters the number of nuclei which participate in self-assembly with pyrrole/schiff base ditopic ligands. The bulky benzyl ester substituents favor formation of di- and tetranuclear (but not trinuclear) complexes.
Publikováno v:
Chemical Communications. 54:11693-11696
A salophen ligand derivative incorporating naphthalene (naphthylsalophen = [H2L]) and the corresponding uranyl (UO22+) complex have been synthesized and characterized both in solution and the solid-state. A hydrogen bonding uranyl tetramer and the el
Publikováno v:
Organometallics. 36:4626-4634
The synthesis and characterization of a new ligand system combining the redox-active backbone of Ar-BIANs (N,N′-bis[(aryl)imino]acenaphthenes) and a mixed-donor O–N–N–O salen-type binding pocket is reported. Complexes of Co2+, Ni2+, and UO22+
Publikováno v:
Inorganic chemistry. 58(22)
Uranyl complexes of aryl-substituted α-diimine ligands gbha (UO2-1a-f) and phen-BIAN (UO2-2a-f) [gbha (1) = glyoxal bis(2-hydroxyanil); phen-BIAN (2) = N,N'-bis(iminophenol)acenaphthene; R = OMe (a), t-bu (b), H (c), Me (d), F (e), and naphthyl (f)]