Zobrazeno 1 - 5
of 5
pro vyhledávání: '"Julian Spils"'
Publikováno v:
Beilstein Journal of Organic Chemistry, Vol 19, Iss 1, Pp 27-32 (2023)
We describe a multi-step continuous-flow procedure for the generation of six-membered diaryliodonium salts. The accompanying scalability and atom economy are significant improvements to existing batch methods. Benzyl acetates are submitted to this tw
Externí odkaz:
https://doaj.org/article/58e263806e4643b28de3c93d7a47df66
Autor:
Daniel Duvinage, Farzin Mostaghimi, Mattis Damrath, Julian Spils, Pascal Komorr, Danila S. Odintsov, Matvey Fedin, Leonid A. Shundrin, Stefan Mebs, Jens Beckmann
Publikováno v:
Chemistry (Weinheim an der Bergstrasse, Germany).
Sterically encumbered bis(m-terphenyl)chalcogenides, (2,6-Mes2C6H3)E (E = S, Se, Te) were obtained by the reaction of the chalcogen tetrafluorides, EF4, with three equivalents of m-terphenyl lithium, 2,6-Mes2C6H3Li. The single electron oxidation of (
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::43a18ffba07e0f016bffcdf0cb141a4e
https://pubmed.ncbi.nlm.nih.gov/36416222
https://pubmed.ncbi.nlm.nih.gov/36416222
We describe a multi-step continuous-flow procedure for the generation of six-membered diaryliodonium salts. The accompanying scalability and atom economy are significant improvements to existing batch methods. Benzyl acetates are submitted to this tw
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::238aee686ed50f0bb7e03a07fae08579
https://doi.org/10.26434/chemrxiv-2022-9q4px
https://doi.org/10.26434/chemrxiv-2022-9q4px
Publikováno v:
The Journal of Organic Chemistry. 85:9161-9178
Two one-pot procedures for the construction of carbon-bridged diaryliodonium triflates and tetrafluoroborates are described. Strong Bronsted acids enable the effective Friedel-Crafts alkylation with diversely substituted o-iodobenzyl alcohol derivati
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e83b1e08cc5aa1c05f0600fde214c5b0
https://doi.org/10.1021/acs.joc.0c01125
https://doi.org/10.1021/acs.joc.0c01125
In this article we describe an efficient approach for the synthesis of cyclic diaryliodonium salts. The method is based on benzyl alcohols as starting materials and consists of an Friedel-Crafts-arylation/oxidation sequence. Besides a deep optimizati
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::04d6b4754df70565bf9a8b30d5e1051c
https://doi.org/10.26434/chemrxiv.12234665
https://doi.org/10.26434/chemrxiv.12234665