A High‐Valent Non‐Heme μ‐Oxo Manganese(IV) Dimer Generated from a Thiolate‐Bound Manganese(II) Complex and Dioxygen

Autor: Abayomi S. Faponle, Christian Philouze, Deborah Brazzolotto, Marcello Gennari, Sam P. de Visser, Julian Smith‐Jones, Kallol Ray, Fabián G. Cantú Reinhard, Carole Duboc, Marius Retegan, Lucia Amidani

Publikováno v: Angewandte Chemie International Edition
Angewandte Chemie International Edition, Wiley-VCH Verlag, 2017, 56 (28), pp.8211-8215. ⟨10.1002/anie.201703215⟩
Angewandte Chemie International Edition, 2017, 56 (28), pp.8211-8215. ⟨10.1002/anie.201703215⟩

International audience; This study deals with the unprecedented reactivity of dinuclear non-heme MnII -thiolate complexes with O2 , which dependent on the protonation state of the initial MnII dimer selectively generates either a di-μ-oxo or μ-oxo-

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::076373aae9986ed3dc77ecac8113ad7a
https://doi.org/10.1002/ange.201703215