Zobrazeno 1 - 10
of 12
pro vyhledávání: '"Julia M. Bayne"'
Autor:
Manuel Alcarazo, Timothy C. Johnstone, Christian W. Lehmann, Douglas W. Stephan, Julia M. Bayne, Alejandro G Barrado
Publikováno v:
Dalton Transactions. 46:16216-16227
Two strategies were used to prepare dicationic phosphonium cations. The first method consists of the reaction of 1-chlorocyclopropenium salts with phosphines to obtain cyclopropenium-substituted phosphonium salts 10a–f[BF4]. Anion exchange was perf
Autor:
Douglas W. Stephan, Julia M. Bayne
Publikováno v:
Chemistry – A European Journal. 25
Autor:
Julia M. Bayne, Douglas W. Stephan
Publikováno v:
Chemistry (Weinheim an der Bergstrasse, Germany). 25(40)
The activation and functionalization of C-F bonds has garnered significant attention in the scientific community as a strategy to mitigate toxicity and environmental concerns, as well as provide new pathways to agro- and pharmaceutical chemicals and
Publikováno v:
Dalton Transactions. 45:5949-5957
Using commercially available 2-pyridyldiphenylphosphine (o-NC5H4)PPh2, a family of electrophilic phosphonium cations [(o-NC5H4)PFPh2](+) (2) and dications [(o-MeNC5H4)PRPh2](2+) (R = F (4); Me (5)) were prepared. The Lewis acidity of these pyridinium
Autor:
Serge I. Gorelsky, David A. Dixon, R. Tom Baker, Julia M. Bayne, Monica Vasiliu, Ilia Korobkov, Matthew C. Leclerc, Daniel J. Harrison, Graham M. Lee
Publikováno v:
Journal of the American Chemical Society. 137:16064-16073
Four perfluoroalkyl cobalt(III) fluoride complexes have been synthesized and characterized by elemental analysis, multinuclear NMR spectroscopy, X-ray crystallography, and powder X-ray diffraction. The remarkable cobalt fluoride (19)F NMR chemical sh
Publikováno v:
Bayne, J M, Fasano, V, Szkop, K M, Ingleson, M J & Stephan, D W 2018, ' Phosphorous(v) Lewis acids : Water/base tolerant P 3-trimethylated trications ', Chemical Communications, vol. 54, no. 88, pp. 12467-12470 . https://doi.org/10.1039/c8cc06564k
The water/base intolerance of the previously reported electrophilic phosphonium cations has been overcome by replacing the labile electron-withdrawing groups generally attached to phosphorus (e.g. -F, -OAr, -CF3) with methyl groups. Tri-phosphorus(v)
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6a335b61966e39ea9d186d0953897af6
https://hdl.handle.net/2434/952289
https://hdl.handle.net/2434/952289
Autor:
Julia M. Bayne, Valerio Fasano, Douglas W. Stephan, James H. W. LaFortune, Michael J. Ingleson
Publikováno v:
Chemical communications (Cambridge, England). 54(6)
A new class of electrophilic phosphonium cations (EPCs) containing a –CF3 group attached to the phosphorus(V) center is readily accessible in high yields, via a scalable process. These species are stable to air, water, alcohol and strong Bronsted a
Publikováno v:
Chemical communications (Cambridge, England). 53(100)
The electrophilic pyridinium-substituted phenoxy-phosphonium dicationic salt [(PhO)P(2-(N-Mepy))Ph2][B(C6F5)4]2, is shown to be an effective catalyst for the double hydroarylation of alkynes with diarylamines to afford a series of 9-methyl-9-aryl-9,1
Autor:
Ian S. Butler, Mauro Henrique Dartora, Rafael M. Lattuada, Julia M. Bayne, Leandra Franciscato Campo, Claudio Radtke, Cícero Coelho de Escobar, João Henrique Zimnoch dos Santos
Publikováno v:
Journal of Sol-Gel Science and Technology. 72:260-272
A series of silica xerogels having rhodamine B (RhB) as a template and Ti centers were synthesized by distinct sol–gel routes, namely, acid-catalyzed, base-catalyzed, acid-catalyzed with base-catalyzed (two steps) hydrolytic routes and a FeCl3-cata
Autor:
Julia M. Bayne, Ian S. Butler
Publikováno v:
Spectroscopy Letters. 47:616-620
Variable-temperature (−150°C to 600°C) and high-pressure (up to ∼5 GPa) micro-Raman spectra have been obtained for the mineral wulfenite [lead(II) molybdate(VI), PbMoO4], a main constituent of the artists' pigment, orange molybdate. The spectra