Zobrazeno 1 - 10
of 30
pro vyhledávání: '"Judith Wölk"'
Autor:
Ashutosh Bhabhe, Alexandra Manka, Reinhard Strey, Kelley Anne Mullick, Barbara E. Wyslouzil, Judith Wölk
Publikováno v:
The Journal of Physical Chemistry B. 119:9009-9019
We follow the nucleation of n-alcohols, n-propanol through n-pentanol, in two sets of supersonic nozzles having differing linear expansion rates. Combining the data from static pressure trace measurements with small-angle X-ray scattering we report t
Publikováno v:
The Journal of Physical Chemistry A. 108:4365-4377
We make direct measurements of stationary, homogeneous nucleation rates, J = N/Δt, in supersonic Laval nozzles. We determine the number densities, N, of droplets formed from small-angle neutron scattering (SANS) experiments and the time intervals du
Publikováno v:
The Journal of Chemical Physics. 118:5465-5473
Small angle neutron scattering (SANS) experiments were used to characterize binary nanodroplets composed of D2O and H2O. The droplets were formed by expanding dilute mixtures of condensible vapor in a N2 carrier gas through a supersonic nozzle, while
Publikováno v:
The Journal of Chemical Physics. 117:6176-6185
We examined the condensation of H2O, D2O, and four intermediate mixtures (20, 40, 60, and 80 mol % D2O) in a supersonic nozzle. Because the physical and chemical properties of protonated and deuterated water are so similar, this system is ideal for s
Publikováno v:
The Journal of Chemical Physics. 117:4954-4960
Very recently, Wolk and Strey [J. Phys. Chem. B 105, 11683 (2001)] presented empirical temperature correction functions for calculating homogeneous nucleation rates J of H2O and D2O (1
Autor:
Antti-Pekka Hyvärinen, Kimmo Neitola, Hanna Görke, David Brus, Judith Wölk, Heikki Lihavainen, Reinhard Strey
Publikováno v:
The Journal of chemical physics. 140(17)
Nucleation rates of n-propanol were investigated in the Laminar Flow Diffusion Chamber. Nucleation temperatures between 270 and 300 K and rates between 10(0) and 10(6) cm(-3) s(-1) were achieved. Since earlier measurements of n-butanol and n‑pentan
Autor:
Judith Wölk and, Reinhard Strey
Publikováno v:
The Journal of Physical Chemistry B. 105:11683-11701
In the past century, the homogeneous nucleation of light water (H2O) has repeatedly been studied using various experimental techniques. Generally, the onset of nucleation was recorded, while less f...
Publikováno v:
AIP Conference Proceedings.
We study the co-condensation of nonane and D2O in a supersonic flow, using small angle X-ray scattering to characterize the size and number density of the aerosol and Fourier Transform Infrared Spectroscopy to determine the composition. Under our exp
Publikováno v:
AIP Conference Proceedings.
New measurements of homogeneous nucleation onset data for argon and nitrogen from the cryogenic nucleation pulse chamber have been performed. By reducing the amount of carrier gas in the gas mixture, higher onset pressures and temperatures could be r
Publikováno v:
AIP Conference Proceedings.
We provide a brief overview of the extensive scientific research that has been conducted to determine the degree to which pure water can be supercooled and the rates at which the relevant phase transitions occur. Beginning with condensation, we prese