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pro vyhledávání: '"Joy Farnaby"'
Double glass transitions in single-component homogeneous liquids due to intramolecular vitrification
Autor:
Ben Russell, Mario González-Jiménez, Nikita Tukachev, Laure-Anne Hayes, Tajrian Chowdhury, Uroš Javornik, Gregor Mali, Manlio Tassieri, Joy Farnaby, Hans Senn, Klaas Wynne
On supercooling a liquid, the viscosity rises rapidly until at the glass transition it vitrifies into an amorphous solid accompanied by a steep drop in the heat capacity. Therefore, a pure homogeneous liquid is not expected to display more than one g
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::68b845f226a750d77cf3162e1cef78ee
https://doi.org/10.26434/chemrxiv-2022-zrbgt-v3
https://doi.org/10.26434/chemrxiv-2022-zrbgt-v3
Publikováno v:
Australian Journal of Chemistry. 75:660-675
The unsubstituted bis-hydrotris(1-pyrazolyl)borate) (Tp) ligand framework has been used to synthesise a range of heteroleptic Ln(III) coordination complexes [Ln(Tp)2(X)]. The precursor complexes [Ln(Tp)2(OTf)] 1-Ln (Ln = Y, Eu, Gd, Yb; OTf = triflate
Autor:
Ben Russell, Nikita Tukachev, Mario González-Jiménez, Laure-Anne Hayes, Tajrian Chowdhury, Uroš Javornik, Gregor Mali, Joy Farnaby, Manlio Tassieri, Hans Senn, Klaas Wynne
At the glass transition, a supercooled liquid vitrifies into an amorphous solid and all viscous relaxation processes cease. The experimental observation of secondary or β relaxations below the glass transition temperature in molecular and metallic g
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6231a4d7b376f9c893e8e1a53ccfc04b
https://doi.org/10.26434/chemrxiv-2022-zrbgt
https://doi.org/10.26434/chemrxiv-2022-zrbgt