Crowding out: ligand modifications and their structure directing effects on brucite-like {M x (μ 3 -OH) y } (M = Co( ii ), Ni( ii )) core growth within polymetallic cages

Autor: Leigh F. Jones, Helen M. O'Connor, Mateusz B. Pitak, Mari E. Slater-Parry, Anne-Laure Barra, Wim T. Klooster, Simon J. Coles, Joshua M. Howells, James P. Durrant, Peter N. Horton, Euan K. Brechin

Publikováno v: Dalton Transactions
Dalton Transactions, Royal Society of Chemistry, 2019, 48 (4), pp.1477-1488. ⟨10.1039/c8dt04229b⟩
Slater-Parry, M E, Durrant, J P, Howells, J M, Pitak, M B, Horton, P N, Klooster, W T, Coles, S J, O'Connor, H M, Brechin, E K, Barra, A-L & Jones, L F 2019, ' Crowding out : ligand modifications and their structure directing effects on brucite-like {M-x((3)-OH)(y)} (M = Co(ii), Ni(ii)) core growth within polymetallic cages ', Dalton Transactions, vol. 48, no. 4, pp. 1477-1488 . https://doi.org/10.1039/C8DT04229B

International audience; Previous employment of the ligands 2-methoxy-6-[(methylimino)methyl]phenol (L1H) and 2-methoxy-6-[(phenylimino)methyl]phenol (L2H) has resulted in the self-assembly of pseudo metallocalix[6]arene complexes of general formulae:

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