Zobrazeno 1 - 10
of 25
pro vyhledávání: '"Joshua I, Bates"'
Publikováno v:
Inorganic Chemistry. 55:5071-5078
The abnormal reaction of phosphaalkenes with N-heterocyclic carbenes (NHC) offers a convenient method to introduce new functionality at the backbone of an NHC. The 4-phosphino-substituted NHC (1a) derived from 1,3-dimesitylimidazol-2-ylidene (IMes) a
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f1040b1510f816026bbd6870baaa1f41
https://doi.org/10.1021/acs.inorgchem.6b00686
https://doi.org/10.1021/acs.inorgchem.6b00686
Publikováno v:
Chemistry - A European Journal. 20:16721-16731
Strategies for the synthesis of highly electrophilic Au(I) complexes from either hydride- or chloride-containing precursors have been investigated by employing sterically encumbered Dipp-substituted expanded-ring NHCs (Dipp=2,6-iPr2 C6 H3 ). Thus, co
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3f435131feab22b22f900891042a9294
https://doi.org/10.1002/chem.201404939
https://doi.org/10.1002/chem.201404939
Publikováno v:
Journal of Organometallic Chemistry. :487-493
Synthetic studies illustrate the crucial roles played by the steric and electronic properties of both the metal-bound ancillary ligands, L, and the boron-bound substituents, X, in the structural and reaction chemistry of boryl (LnMBX2) and borylene s
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::2f6c4e8bb4843d419a2fbbe4aaf7bcec
https://doi.org/10.1016/j.jorganchem.2012.05.005
https://doi.org/10.1016/j.jorganchem.2012.05.005
Publikováno v:
Organometallics. 32:1583-1586
Systems of the type [(p-cym)Ru(PR3)(H)(H2BNiPr2)]+ (R = Cy, Ph) can be synthesized from (p-cym)Ru(PR3)Cl2 and H2BNiPr2/Na[BArf4] and are best formulated as (hydrido)ruthenium κ1-aminoborane complexes. VT-NMR measurements have been used to probe the
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::32ae596674c146e2f5285de6cd4a5368
https://doi.org/10.1021/om400040q
https://doi.org/10.1021/om400040q
Autor:
Michael J. Kelly, Nicholas Phillips, Russell A. Taylor, Dragoslav Vidovic, Juan Urbano, Ian M. Riddlestone, Simon Aldridge, Joshua I. Bates
Publikováno v:
Dalton Trans.. 42:249-258
Salt metathesis has been exploited in the synthesis of M-Al bonds, stabilized by a variety of chelating N-donor substituents at aluminium and including the first examples of such systems featuring ancillary guanidinato frameworks. Importantly, this s
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2b1eab7f33c85999d54b55429fe99c78
https://doi.org/10.1039/c2dt31974h
https://doi.org/10.1039/c2dt31974h
Autor:
Christina Y. Tang, Simon Aldridge, Amber L. Thompson, Nicholas Phillips, Matthias J. Gutmann, Joshua I. Bates
The reactions of Me(2)NH·BH(3) with cationic Rh(III) and Ir(III) complexes have been shown to generate the 18-electron aminoborane adduct [Ir(IMes)(2)(H)(2){κ(2)-H(2)BNMe(2))](+) and the remarkable 14-electron aminoboryl complex [Rh(IMes)(2)(H)-{B(
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c334dd85e23b4e322fb137248d448920
https://doi.org/10.1039/c2cc33361a
https://doi.org/10.1039/c2cc33361a
Autor:
Simon Aldridge, Michael J. Kelly, Juan Urbano, Siân Edmonds, Joshua I. Bates, Russell A. Taylor, Paul A. Kaufman, Ian M. Riddlestone, Amber L. Thompson
Photolytic ligand displacement and salt metathesis routes have been exploited to give access to κ(1) σ-alane complexes featuring Al-H bonds bound to [W(CO)(5)] and [Cp'Mn(CO)(2)] fragments, together with a related κ(2) complex of [Cr(CO)(4)]. Spec
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::94838cae6aea94473b04f41f7a4c9c5c
https://ora.ox.ac.uk/objects/uuid:9bc77dc6-d279-445b-9a18-d8ea5a40165d
https://ora.ox.ac.uk/objects/uuid:9bc77dc6-d279-445b-9a18-d8ea5a40165d
Autor:
Andrey V, Protchenko, Joshua I, Bates, Liban M A, Saleh, Matthew P, Blake, Andrew D, Schwarz, Eugene L, Kolychev, Amber L, Thompson, Cameron, Jones, Philip, Mountford, Simon, Aldridge
Publikováno v:
Journal of the American Chemical Society. 138(13)
By employing strongly σ-donating boryl ancillary ligands, the oxidative addition of H2 to a single site Sn(II) system has been achieved for the first time, generating (boryl)2SnH2. Similar chemistry can also be achieved for protic and hydridic E-H b
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::240576b3dbb62b99a22e7a92533d4db7
https://pubmed.ncbi.nlm.nih.gov/26981766
https://pubmed.ncbi.nlm.nih.gov/26981766
Autor:
Derek P. Gates, Joshua I. Bates
Publikováno v:
Organometallics. 31:4529-4536
The activation of the P═C bond of phosphaalkenes with N-heterocyclic carbenes (NHCs) offers a convenient means to introduce new functionality at the 4-position of an NHC. Treatment of MesP═CRR′ (2a: R = R′ = Ph; 2b: R = Ph, R′ = 2-C5H4N; 2c
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::353268131d916e281ce85400a3281060
https://doi.org/10.1021/om3003174
https://doi.org/10.1021/om3003174
Publikováno v:
Dalton Trans.. 39:3151-3159
Many parallels have been drawn between the chemistry of low-valent phosphorus and carbon. This Perspective is intended to highlight some emerging reactivity of phosphaalkenes, that is phospha-analogues of alkenes, in the areas of asymmetric catalysis
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::bb0216fedb66d64f62a1eebc6022a543
https://doi.org/10.1039/b918938f
https://doi.org/10.1039/b918938f