Zobrazeno 1 - 10
of 27
pro vyhledávání: '"Joshua A. Buss"'
Publikováno v:
Inorganic Chemistry. 61:7710-7714
Publikováno v:
ACS Catalysis. 11:13294-13302
The reaction chemistry of both silanes and hydrogen at para-terphenyl diphosphine-supported molybdenum complexes was explored within the context of carbon dioxide (CO₂) reduction. CO₂ hydrosilylation commonly affords reduction products via silyl
Publikováno v:
Organic Letters. 22:5749-5752
A copper catalyst in combination with N-fluorobenzenesulfonimide (NFSI) has been reported to functionalize benzylic C-H bonds to the corresponding benzylic sulfonimides via C-N coupling. Here, we reported a closely related Cu-catalyzed method with NF
Publikováno v:
Org Lett
Site-selective chlorination of benzylic C─H bonds is achieved using a Cu(I)Cl/bis(oxazoline) catalyst with N-fluorobenzenesulfonimide as the oxidant and KCl as a chloride source. This method exhibits higher benzylic selectivity relative to establis
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::825926859e9fb9968df35c8842d086a8
https://europepmc.org/articles/PMC8830506/
https://europepmc.org/articles/PMC8830506/
Open-shell compounds bearing metal–carbon triple bonds, such as carbides and carbynes, are of significant interest as plausible intermediates in the reductive catenation of C₁ oxygenates. Despite the abundance of closed-shell carbynes reported, o
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9304af6c51f88d01a3e0e8090c59c508
https://resolver.caltech.edu/CaltechAUTHORS:20210831-200226268
https://resolver.caltech.edu/CaltechAUTHORS:20210831-200226268
Autor:
Gwendolyn A. Bailey, Joshua A. Buss, William A. Goddard, Julius Oppenheim, Theodor Agapie, David G. VanderVelde
Publikováno v:
Journal of the American Chemical Society. 141:15664-15674
The mechanism originally proposed by Fischer and Tropsch for carbon monoxide (CO) hydrogenative catenation involves C–C coupling from a carbide-derived surface methylidene. A single molecular system capable of capturing these complex chemical steps
Publikováno v:
Org Lett
A copper catalyst in combination with N-fluorobenzenesulfonimide (NFSI) has been reported to functionalize benzylic C–H bonds to the corresponding benzylic sulfonimides via C–N coupling. Here, we reported a closely related Cu-catalyzed method wit
Publikováno v:
Org Lett
Site-selective transformation of benzylic C-H bonds into diverse functional groups is achieved via Cu-catalyzed C-H fluorination with N-fluorobenzenesulfonimide (NFSI), followed by substitution of the resulting fluoride with various nucleophiles. The
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::20717af6994be59fa2ba971da7d25a04
https://europepmc.org/articles/PMC7446105/
https://europepmc.org/articles/PMC7446105/
Autor:
Mukunda Mandal, Christopher J. Cramer, Saied Md Pratik, Shannon S. Stahl, Shane W. Krska, Joshua A. Buss, Si Jie Chen, Huayou Hu
Publikováno v:
Nature catalysis
Cross-coupling reactions enable rapid, convergent synthesis of diverse molecules and provide the foundation for modern chemical synthesis. The most widely used methods employ sp2-hybridized coupling partners, such as aryl halides or related pre-funct
Publikováno v:
Journal of the American Chemical Society. 140:10121-10125
Though Lewis acids (LAs) have been shown to have profound effects on carbon dioxide (CO2) reduction catalysis, the underlying cause of the improved reactivity remains unclear. Herein, we report a well-defined molecular system for probing the role of