Zobrazeno 1 - 10
of 44
pro vyhledávání: '"Joseph W. Holubka"'
Publikováno v:
Journal of Coatings Technology. 72:39-45
This paper focuses on defining the reaction mechanism involved in the environmental etch of acrylic melamine-based automotive clearcoats via an identification of reaction products. This has been accomplished through a comparative study of products fo
Autor:
Larry P. Haack, Joseph W. Holubka
Publikováno v:
Journal of Coatings Technology. 72:63-70
The interplay of bake oven processing environment and surface/interfacial chemistry, and their effect on intercoat adhesion has been investigated for a model primer/electrocoat paint system. X-ray photoelectron spectroscopy (XPS) surface analysis est
Publikováno v:
Journal of Coatings Technology. 72:53-61
A laboratory test procedure was developed to quantitatively evaluate the acid etch resistance of automotive clearcoats. Here we attempt to verify that the conditions used in the laboratory test reproduce the field degradation chemistry to assure that
Publikováno v:
Journal of Coatings Technology. 72:77-82
This paper reports on the development of a laboratory test procedure for the evaluation of the environmental etch resistance of clearcoats. The test evaluates the bulk acid hydrolysis resistance of clearcoats by gravimetrically following material wei
Autor:
Joseph W. Holubka, Alekh S. Bhurke, Lawrence T. Drzal, Ming Xie, Larry P. Haack, Ann Marie Straccia
Publikováno v:
Surface and Interface Analysis. 29:829-836
Surface modification using UV/ozone was explored as an approach towards ensuring robust intercoat adhesion in multilayered automotive coating systems. This study was directed toward reducing the variability in adhesion performance associated with cha
Publikováno v:
Surface and Interface Analysis. 25:643-649
In this study we evaluate the utility of using x-ray-excited valence band measurements for the determination of the surface composition of simple model thermoplastic olefin systems composed of binary blends of semicrystalline polypropylene (PP) and a
Autor:
J. E. deVries, Larry P. Haack, Joseph W. Holubka, John L. Gerlock, Ray A. Dickie, T. J. Prater, S. L. Kaberline, J. Chakel
Publikováno v:
Progress in Organic Coatings. 25:95-108
Two examples of recent advances in spatially resolved surface analytical characterization of paint and adhesive chemistries are presented. The examples extend previous analytical capabilities by combining the molecular specificity and bonding informa
Autor:
Joseph W. Holubka, H. Bernhard Schlegel, Jose L. Andres, Julia E. Winter, James C. Ball, Robert D. Bach
Publikováno v:
Journal of Adhesion Science and Technology. 8:249-259
The interactions between paint/adhesive polymers and metal surfaces that are critical for adhesion have been studied theoretically. This study used zinc oxide as a model of a galvanized steel surface, and ammonia, water, and ethylene as models for am
Publikováno v:
Macromolecules. 25:1189-1192
Molecular orbital calculations show that a water molecule exerts a significant catalytic activity upon the rate of oxirane cleavage by the nucleophile. The trend established upon going from no proton donor, to weakly acidic water, to a fully protonat
Autor:
Joseph W. Holubka, Joseph J. W. McDouall, James C. Ball, Amy L. Owensby, H. Bernhard Schlegel, Robert D. Bach
Publikováno v:
Journal of Physical Organic Chemistry. 4:125-134
Ab initio MO methods have been used to study the structures and energetics of dicyandiamide, [(NH2)2CNCN], its isomers, protonated species, radical anions, transition structures for internal conformational change and transition structures for isomeri