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pro vyhledávání: '"Joseph P. Dowling"'
Publikováno v:
Journal of the American Chemical Society. 120:2290-2296
The third-order term (kAB) for the concerted acid−base catalyzed enolization of a selection of simple aldehydes and ketones has been measured in a series of substituted acetic acids at 25 °C at constant ionic strength 2.0 (NaNO3). While there is n
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::2c336f73b5c471194cfef8fbd8f0c936
https://doi.org/10.1021/ja9729544
https://doi.org/10.1021/ja9729544
Autor:
Joseph P. Dowling, Anthony F. Hegarty
Publikováno v:
Journal of the Chemical Society, Chemical Communications. :996
At high buffer concentrations the enolisation of aldehydes is markedly catalysed simultaneously by acidic and basic species; the magnitude of the ‘third-order term’ can be related directly to the importance of the individual acid and base catalys
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::f4d6c26e2f4a960ef458032df489bf9c
https://doi.org/10.1039/c39910000996
https://doi.org/10.1039/c39910000996