Zobrazeno 1 - 10 of 175 pro vyhledávání: '"Jose M. Goicoechea"'
1
Putting cyaphide in its place: determining the donor/acceptor properties of the κC-cyaphido ligand
Autor: Eric S. Yang, Emma Combey, Jose M. Goicoechea
Publikováno v: Chemical Science. 14:4627-4632
The σ-donor and π-acceptor properties of the cyaphide ion (CP–) are compared to other well-established strong-field ligands allowing us to assess the relative position of this unique ion in the spectrochemical series.
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::372aa0bbcc0a5bd6d554110662a67b6d
https://doi.org/10.1039/d3sc01126g
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2
Coordination and Homologation of CO at Al(I): Mechanism and Chain Growth, Branching, Isomerization, and Reduction
Autor: Andreas Heilmann, Matthew M. D. Roy, Agamemnon E. Crumpton, Liam P. Griffin, Jamie Hicks, Jose M. Goicoechea, Simon Aldridge
Publikováno v: Journal of the American Chemical Society. 144:12942-12953
Homologation of carbon monoxide is central to the heterogeneous Fischer-Tropsch process for the production of hydrocarbon fuels. C-C bond formation has been modeled by homogeneous systems, with [C
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::aaf1d3d9a4f4749f470d03e478b99cff
https://doi.org/10.1021/jacs.2c05228
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5
The Chemistry of the Cyaphide Ion
Autor: Tim Görlich, Peter Coburger, Eric S. Yang, Jose M. Goicoechea, Hansjörg Grützmacher, Christian Müller
Publikováno v: Angewandte Chemie. International Edition
We review the known chemistry of the cyaphide ion, (C=P)(-). This remarkable diatomic anion has been the subject of study since the late nineteenth century, however its isolation and characterization eluded chemists for almost a hundred years. In thi
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f8737e54e3d9f7bf8ab6bad6cbaf8fdf
https://doi.org/10.1002/anie.202217749
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6
An Aluminium Imide as a Transfer Agent for the [NR] 2− Function via Metathesis Chemistry
Autor: Andreas Heilmann, Petra Vasko, Jamie Hicks, Jose M. Goicoechea, Simon Aldridge
Publikováno v: Chemistry – A European Journal. 29
The reactions of a terminal aluminium imide with a range of oxygen-containing substrates have been probed with a view to developing its use as a novel main group transfer agent for the [NR]2- fragment. We demonstrate transfer of the imide moiety to [
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b937edb9f096a09653b4bbb744b3205f
https://doi.org/10.1002/chem.202300018
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8
Pincer‐Supported Gallium Complexes for the Catalytic Hydroboration of Aldehydes, Ketones and Carbon Dioxide
Autor: Siu-Kwan Lo, Lingyu Liu, Jose M. Goicoechea, Cory Smith
Publikováno v: Chemistry – A European Journal. 27:17379-17385
Gallium hydrides stabilised by primary and secondary amines are scarce due to their propensity to eliminate dihydrogen. Consequently, their reactivity has received limited attention. The synthesis of two novel gallium hydride complexes HGa(THF)[ON(H)
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0990453a2e7cf5eb212ab77ea4357cbf
https://doi.org/10.1002/chem.202103009
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9
Thermoneutral N−H Bond Activation of Ammonia by a Geometrically Constrained Phosphine
Autor: Oliver P. E. Townrow, Jose M. Goicoechea, Josh Abbenseth
Publikováno v: Angewandte Chemie (International Ed. in English)
A geometrically constrained phosphine bearing a tridentate NNS pincer ligand is reported. The effect of the geometric constraint on the electronic structure was probed by theoretical calculations and derivatization reactions. Reactions with N−H bon
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b7e87cf7fda7404c704d22ec0d8aef14
https://doi.org/10.1002/ange.202111017
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