Zobrazeno 1 - 10
of 115
pro vyhledávání: '"Jose‐Luis Garcia Ruano"'
Autor:
Romano Dorta, Alberto Herrera, Vikas Sikervar, Jose Luis Garcia Ruano, Ahmed Chelouan, J. Alemán
Publikováno v:
Encyclopedia of Reagents for Organic Synthesis. :1-12
Autor:
Francisco Yuste, Jose Luis Garcia Ruano, José Alemán, Rubén A. Toscano, Rubén Sánchez-Obregón, Ana M. Martin Castro, Inés Alonso, Ignacio Pérez, Leyre Marzo
Publikováno v:
European Journal of Organic Chemistry. 2015:3314-3319
Diastereoselective quaternization of ortho-sulfinylbenzyl-methylpropargylic carbanions has been carried out with various allylic, propargylic, and benzylic halides. The stereoselectivity is efficiently controlled by the sulfinyl group, acting as a re
Publikováno v:
The Journal of Organic Chemistry. 78:10737-10746
An asymmetric organocatalytic [3 + 3] annulation strategy based on a Michael addition/intramolecular Julia-Kocienski olefination sequence has been developed for the synthesis of 4-substituted-5-nitrocyclohex-1-ene compounds. The strategy is an altern
Publikováno v:
European Journal of Organic Chemistry. 2013:4405-4409
The reaction of metal alkoxides with β-substituted 2-(p-tolylsulfonyl)acetylenes, involving an anti-Michael addition reaction followed by the in situ elimination of the sulfonyl moiety, provides a direct method for the synthesis of alkyl alkynyl eth
Autor:
M. Carmen Maestro, José A. Fernández-Salas, Jose Luis Garcia Ruano, M. Mercedes Rodriguez‐Fernandez
Publikováno v:
European Journal of Organic Chemistry. 2013:1796-1804
Reactions of α-[2-(p-tolylsulfinyl)phenyl] α-methylidene carbonyl compounds 1 and 2 with alkyl radicals generated from Et3B/O2 and RI give, after protonation, β-alkyl derivatives with a high degree of control of the configuration at the α carbon.
Publikováno v:
Synthetic Communications. 43:198-207
Raney-Ni/EtOH reduction of different N-sulfonylimines provides a new entry for synthesizing sulfonamides in good yields under mild conditions. This protocol, which does not require additional hydrogen, constitutes a cheap, safe, and easy-to-handle al
Publikováno v:
The Journal of Organic Chemistry. 77:6583-6599
In this work, we report the use of the asymmetric intramolecular Pauson-Khand reactions of 4-aryl-4-cyano-1,6-enynes for obtaining enantiomerically enriched bicyclo[3.3.0]octenones, and the influence of both the quaternary stereocenter and the sulfur
Publikováno v:
Chemistry - A European Journal. 18:9775-9779
Allenes are important compounds that exhibit axial chirality and are present in a large number of medicinal and natural products. One of the most frequently used methods for obtaining racemic allenes involves the isomerization of propargylic centers.
Autor:
Cristina Izquierdo, Jose Luis Garcia Ruano, Sergio Díaz-Tendero, Leyre Marzo, Alberto Fraile, José Alemán
Publikováno v:
Advanced Synthesis & Catalysis. 354:1665-1671
The first organocatalytic enantioselective 1,3-dipolar reaction between nitrones and alkynals catalyzed by (S)-2-(fluorodiphenylmethyl)pyrrolidine to give 4-isoxazolines (2,3-dihydroisoxazoles) with high enantiomeric excess, excellent yields and low
Autor:
Alberto Fraile, José Alemán, Sergio Díaz-Tendero, Mariola Tortosa, Jose Luis Garcia Ruano, Leyre Marzo, Cuauhtemoc Alvarado
Publikováno v:
Chemistry – A European Journal. 18:8414-8422
We describe the unexpected behavior of the arylsulfonylacetylenes, which suffer an "anti-Michael" addition of organolithiums producing their alkynylation under very mild conditions. The broad scope, excellent yields, and simplicity of the experimenta