Azole-containing cationic bis-cyclometallated iridium(iii) isocyanide complexes: a theoretical insight into the emission energy and emission efficiency

Autor: Angelo Giussani, José M. Junquera-Hernández, Paula Pla, Enrique Ortí

Publikováno v: Dalton Transactions. 48:9725-9733

Using a density functional theory approach, we explore the emission properties of a family of bis-cyclometallated cationic iridium(iii) complexes of general formula [Ir(C^N)2(CN-tert-Bu)2]+ that have tert-butyl isocyanides as neutral auxiliary ligand

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e9326506c286075cb1c6b12448475379
https://doi.org/10.1039/c9dt00412b

CF3 Substitution of [Cu(P^P)(bpy)][PF6 ] Complexes: Effects on Photophysical Properties and Light-Emitting Electrochemical Cell Performance

Autor: Henk J. Bolink, Fabian Brunner, Catherine E. Housecroft, Enrique Ortí, Antonio Pertegás, Alessandro Prescimone, Edwin C. Constable, Sarah Keller, José M. Junquera-Hernández, Maria-Grazia La-Placa

Publikováno v: ChemPlusChem. 83:217-229

Herein, [Cu(P^P)(N^N)][PF6 ] complexes (P^P=bis[2-(diphenylphosphino)phenyl]ether (POP) or 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene (xantphos); N^N=CF3 -substituted 2,2'-bipyridines (6,6'-(CF3 )2 bpy, 6-CF3 bpy, 5,5'-(CF3 )2 bpy, 4,4'-(CF3 )2

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0fd65dc58d21b8c33b85c576c045f94f
https://doi.org/10.1002/cplu.201700501

Luminescent copper(i) complexes with bisphosphane and halogen-substituted 2,2′-bipyridine ligands

Autor: Catherine E. Housecroft, Alessandro Prescimone, Michele Sessolo, Henk J. Bolink, Edwin C. Constable, Enrique Ortí, Laura Martínez-Sarti, Sarah Keller, Giulia Longo, José M. Junquera-Hernández

Publikováno v: Dalton Transactions. 47:14263-14276

Heteroleptic [Cu(P^P)(N^N)][PF6] complexes, where N^N is a halo-substituted 2,2'-bipyridine (bpy) and P^P is either bis(2-(diphenylphosphino)phenyl)ether (POP) or 4,5-bis(diphenylphosphino)-9,9- dimethylxanthene (xantphos) have been synthesized and i

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9851f425c6ce6f3cb962194382ee991b
https://doi.org/10.1039/c8dt01338a

Phosphane tuning in heteroleptic [Cu(N^N)(P^P)]+ complexes for light-emitting electrochemical cells

Autor: Catherine E. Housecroft, Enrique Ortí, José M. Junquera-Hernández, Azin Babaei, Fabian Brunner, Antonio Pertegás, Edwin C. Constable, Alessandro Prescimone, Henk J. Bolink, Michele Sessolo

Publikováno v: Brunner, Fabian Babaei, Azin Pertegás Ojeda, Antonio Junquera-Hernández, José M. Prescimone, Alessandro Constable, Edwin C. Bolink, Henk Sessolo, Michele Ortí Guillén, Enrique Housecroft, Catherine E. 2019 Phosphane tuning in heteroleptic [Cu(N^N)(P^P)]+ complexes for light-emitting electrochemical cells Dalton Transactions 48 2 446 460
RODERIC: Repositorio Institucional de la Universitat de Valéncia
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RODERIC. Repositorio Institucional de la Universitat de Valéncia

The synthesis and characterization of five [Cu(P^P)(N^N)][PF 6 ] complexes in which P^P = 2,7-bis( tert -butyl)-4,5-bis(diphenylphosphino)-9,9-dimethylxanthene ( t Bu 2 xantphos) or the chiral 4,5-bis(mesitylphenylphosphino)-9,9-dimethylxanthene (xan

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::89b71f3081939f899d439e26a4830b7a
https://hdl.handle.net/10550/75141

Regioisomerism in cationic sulfonyl-substituted [Ir(C^N)2(N^N)]+ complexes: its influence on photophysical properties and LEC performance

Autor: José M. Junquera-Hernández, Lidón Gil-Escrig, Markus Neuburger, Henk J. Bolink, Jesús Cerdá, Cathrin D. Ertl, Edwin C. Constable, Antonio Pertegás, Alessandro Prescimone, Enrique Ortí, Catherine E. Housecroft

Publikováno v: Dalton Transactions

A series of regioisomeric cationic iridium complexes of the type [Ir(C^N)2(bpy)][PF6] (bpy = 2,2'-bipyridine) is reported. The complexes contain 2-phenylpyridine-based cyclometallating ligands with a methylsulfonyl group in either the 3-, 4- or 5-pos

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f0c7aaf7e330829b81f316a00749a8b2
https://doi.org/10.1039/c6dt01325b