Templated synthesis of zirconium(iv)-based metal–organic layers (MOLs) with accessible chelating sites

Autor: Pol Gimeno-Fonquernie, Weibin Liang, Jorge Albalad, Andrew Kuznicki, Jason R. Price, Eric D. Bloch, Christian J. Doonan, Christopher J. Sumby

Publikováno v: Chemical Communications. 58:957-960

Metal-organic layers (MOLs) are of great interest in heterogeneous catalysis, particularly materials that can accommodate extraneous metal centres. Here, we demonstrate a two-step preorganisation/delamination synthetic strategy using CuI as a templat

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3fa31b5fbfb55847a72643a243612b5b
https://doi.org/10.1039/d1cc06443f

Surface chemistry of metal-organic polyhedra

Autor: Jorge Albalad, Laura Hernández-López, Arnau Carné-Sánchez, Daniel Maspoch

Publikováno v: Digital.CSIC. Repositorio Institucional del CSIC
instname
Dipòsit Digital de Documents de la UAB
Universitat Autònoma de Barcelona

Metal-organic polyhedra (MOPs) are discrete, intrinsically-porous architectures that operate at the molecular regime and, owing to peripheral reactive sites, exhibit rich surface chemistry. Researchers have recently exploited this reactivity through

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::774c9951c8cbaf8247c6382546b62d5d
http://hdl.handle.net/10261/271192

Synthesis of polycarboxylate rhodium(II) Metal–Organic Polyhedra (MOPs) and their use as building blocks for highly connected Metal–Organic Frameworks (MOFs)

Autor: Farnoosh Zarekarizi, Inhar Imaz, Judith Juanhuix, Daniel Maspoch, Arnau Carné-Sánchez, Ali Morsali, Akim Khobotov, Felipe Gándara, Vincent Guillerm, Thais Grancha, Laura Hernández-López, Jorge Albalad

Publikováno v: Digital.CSIC. Repositorio Institucional del CSIC
instname
Dipòsit Digital de Documents de la UAB
Universitat Autònoma de Barcelona

Use of preformed metal-organic polyhedra (MOPs) as supermolecular building blocks (SBBs) for the synthesis of metal-organic frameworks (MOFs) remains underexplored due to lack of robust functionalized MOPs. Herein we report the use of polycarboxylate

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::051bc84812c51fd2f29f1b76c608de29
http://hdl.handle.net/10261/253064

Postsynthetic Selective Ligand Cleavage by Solid–Gas Phase Ozonolysis Fuses Micropores into Mesopores in Metal–Organic Frameworks

Autor: Daniel Maspoch, Jorge Albalad, Heng Xu, Vincent Guillerm, Inhar Imaz

Publikováno v: Dipòsit Digital de Documents de la UAB
Universitat Autònoma de Barcelona
Journal of the American Chemical Society
Journal of the American Chemical Society, American Chemical Society, 2018, 140 (44), pp.15022-15030. ⟨10.1021/jacs.8b09682⟩
Digital.CSIC. Repositorio Institucional del CSIC
instname

Herein we report a novel, ozone-based method for postsynthetic generation of mesoporosity in metal–organic frameworks (MOFs). By carefully selecting mixed-ligand Zr-fcu-MOFs based on organic ligand pairs in which one ligand has ozone-cleavable olef

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::afe6bd1599417a89d2ca589189822e15
https://doi.org/10.1021/jacs.8b09682

Phase Transfer of Rhodium(II)-Based Metal-Organic Polyhedra Bearing Coordinatively Bound Cargo Enables Molecular Separation

Autor: Daniel Maspoch, Thais Grancha, Jorge Albalad, Arnau Carné-Sánchez, Judith Juanhuix, Inhar Imaz, Laura Hernández-López

Publikováno v: Digital.CSIC. Repositorio Institucional del CSIC
instname
Dipòsit Digital de Documents de la UAB
Universitat Autònoma de Barcelona

The transfer of nanoparticles between immiscible phases can be driven by externally triggered changes in their surface composition. Interestingly, phase transfers can enhance the processing of nanoparticles and enable their use as vehicles for transp

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0efb36b9b44b9e8359d4eabb462e8dc8
https://pubmed.ncbi.nlm.nih.gov/31647663