Electron-Poor Phosphines Enable the Selective Semihydrogenation Reaction of Alkynes with Pd on Carbon Catalysts

Autor: Jordi Ballesteros-Soberanas, Antonio Leyva-Pérez

Publikováno v: The Journal of Physical Chemistry Letters. 14:965-970

An alternative to the Lindlar catalyst for the semihydrogenation reaction of alkynes to alkenes is of high interest. Here we show that palladium on carbon (Pd/C), i.e., a widely available supported Pd catalyst, is converted from an unselective to a c

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::fc0789a8373bef5a0fdad4fafed77bd0
https://doi.org/10.1021/acs.jpclett.2c03428

Parts-Per-Million of Soluble Pd

Autor: Jordi, Ballesteros-Soberanas, Jose A, Carrasco, Antonio, Leyva-Pérez

Publikováno v: The Journal of organic chemistry.

The synthesis of

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::9b572ebd4e69485582b833edd9057d25
https://pubmed.ncbi.nlm.nih.gov/35584367

Selective semi-hydrogenation of internal alkynes catalyzed by Pd–CaCO3 clusters

Autor: Jordi Ballesteros-Soberanas, Juan Carlos Hernández-Garrido, José Pedro Cerón-Carrasco, Antonio Leyva-Pérez

Publikováno v: Digital.CSIC. Repositorio Institucional del CSIC
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The de-novo synthesis of soluble or solid-supported Pd-(CaCO) clusters (n = 2–13) and their high catalytic activity for the semi-hydrogenation of internal alkynes compared to terminal alkynes, is presented. Mechanistic studies show that this reacti

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::785bc58b70c53ed849bb82e9daddd184
http://hdl.handle.net/10261/281415

Effects of Phosphonic Acid Monolayers on the Dehydration Mechanism of Aliphatic Alcohols on TiO2

Autor: Lucas D. Ellis, Jordi Ballesteros-Soberanas, J. Will Medlin

Publikováno v: ACS Catalysis. 9:7808-7816

The kinetics for surface-catalyzed alcohol dehydration reactions often depend on the structure of the alcohol. Studies of structure–activity relations across primary, secondary, and tertiary alcoho...

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::d929c1eec9f8fe70287869deca64ac85
https://doi.org/10.1021/acscatal.9b02082

Soluble/MOF-Supported Palladium Single Atoms Catalyze the Ligand-, Additive-, and Solvent-Free Aerobic Oxidation of Benzyl Alcohols to Benzoic Acids

Autor: Mercedes Boronat, Antonio Leyva-Pérez, Miguel López-Haro, Rossella Greco, Emilio Pardo, Carlo Marini, Jordi Ballesteros-Soberanas, Juan C. Hernández-Garrido, Donatella Armentano, Jesús Ferrando-Soria, Marta Mon, Judit Oliver-Meseguer, Estefanía Tiburcio

Publikováno v: Journal of the American Chemical Society
Tiburcio, Estefanía Greco, Rossella Mon Conejero, Marta Ballesteros-Soberanas, Jordi Ferrando Soria, Jesús López-Haro, Miguel Hernández-Garrido, Juan Carlos Oliver-Meseguer, Judit Marini, Carlo Boronat, Mercedes Armentano, Donatella Leyva-Pérez, Antonio Pardo Marín, Emilio 2021 Soluble/MOF-Supported Palladium Single Atoms Catalyze the Ligand-, Additive-, and Solvent-Free Aerobic Oxidation of Benzyl Alcohols to Benzoic Acids Journal of the American Chemical Society 143 6 2581 2592
RODERIC. Repositorio Institucional de la Universitat de Valéncia
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Digital.CSIC. Repositorio Institucional del CSIC

Metal single-atom catalysts (SACs) promise great rewards in terms of metal atom efficiency. However, the requirement of particular conditions and supports for their synthesis, together with the need of solvents and additives for catalytic implementat

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e1484f9593b044938e21c556efe1be12
https://pubmed.ncbi.nlm.nih.gov/33535758