Výsledky vyhledávání - "Jonathan D. Cryer"

Dipnictogen f-Element Chemistry: A Diphosphorus Uranium Complex

Autor: Ashley J. Wooles, John A. Seed, Joris van Slageren, Stephen T. Liddle, David Hunger, Jingzhen Du, David M. King, Jonathan D. Cryer

Publikováno v: Journal of the American Chemical Society. 143(14)

The first isolation and structural characterization of an f-element dinitrogen complex was reported in 1988, but an f-element complex with the first heavier group 15 homologue diphosphorus has to date remained unknown. Here, we report the synthesis o

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::14692438f2dec3b95bb2b98b51fdfb4c
https://pubmed.ncbi.nlm.nih.gov/33792307

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Back-bonding between an electron-poor, high-oxidation-state metal and poor π-acceptor ligand in a uranium(V)–dinitrogen complex

Autor: Iñigo J. Vitorica-Yrezabal, George F. S. Whitehead, Ashley J. Wooles, Benjamin E. Atkinson, Josef T. Boronski, Nikolas Kaltsoyannis, Stephen T. Liddle, Floriana Tuna, Philip J. Cobb, Jonathan D. Cryer, Laurence R. Doyle, Erli Lu

Publikováno v: Lu, E, Atkinson, B, Wooles, A, Boronski, J, Doyle, L, Tuna, F, Cryer, J, Cobb, P, Vitorica-Yrezabal, I, Whitehead, G, Kaltsoyannis, N & Liddle, S 2019, ' Back-bonding between an electron-poor, high-oxidation-state metal and poor π-acceptor ligand in a uranium(V)–dinitrogen complex ', Nature Chemistry, vol. 11, pp. 806-811 . https://doi.org/10.1038/s41557-019-0306-x

A fundamental bonding model in coordination and organometallic chemistry is the synergic, donor–acceptor interaction between a metal and a neutral π-acceptor ligand, in which the ligand σ donates to the metal, which π back-bonds to the ligand. T

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3dd7cbffb833e4b9e02741a2b5ccaed2
https://pure.manchester.ac.uk/ws/files/112306066/UN2Li_Paper_ACCEPTED.pdf

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