Výsledky vyhledávání - "Jonas C. Ott"

3d Metal Complexes in T-shaped Geometry as a Gateway to Metalloradical Reactivity

Autor: Jonas C. Ott, David Bürgy, Hairong Guan, Lutz H. Gade

Publikováno v: Accounts of Chemical Research. 55:857-868

ConspectusLow-valent, low-coordinate 3d metal complexes represent a class of extraordinarily reactive compounds that can act as reagents and catalysts for challenging bond-activation reactions. The pursuit of these electron-deficient metal complexes

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7fcbc7f447775ae568d9377d4e0e50bb
https://doi.org/10.1021/acs.accounts.1c00737

Zobrazit plný text záznamu

Öffnung der Valenzschale: Ein T‐förmiges Eisen(I)‐Metalloradikal und sein Potential als Atomabstraktor

Autor: Lutz H. Gade, Jonas C. Ott, Hubert Wadepohl

Publikováno v: Angewandte Chemie. 132:9535-9539

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::c0d25be9cabe623f0f8d47a16cc672cd
https://doi.org/10.1002/ange.202003118

Zobrazit plný text záznamu

Single or Paired? Structure and Reactivity of PNP-Chromium(II) Hydrides

Autor: Daniel Isak, Hubert Wadepohl, Jonas C. Ott, Lutz H. Gade, Julian J Melder

Publikováno v: Inorganic chemistry. 59(19)

The preparation and reactivity of a range of novel paramagnetic chromium(II) complexes supported by a carbazole-based PNP pincer ligand is reported. Deprotonation of the ligand precursors R(PNP)H (1R) and subsequent reaction with chromium(II) chlorid

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::84d6ce0a68cc80176885bd195de7c326
https://pubmed.ncbi.nlm.nih.gov/32931701

Zobrazit plný text záznamu

Opening up the Valence Shell: A T-Shaped Iron(I) Metalloradical and Its Potential for Atom Abstraction

Autor: Hubert Wadepohl, Jonas C. Ott, Lutz H. Gade

Publikováno v: Angewandte Chemie (International Ed. in English)

A thermally stable, T‐shaped, d7 high‐spin iron(I) complex was obtained by reduction of a PNP‐supported ferrous chloride. Paramagnetic NMR spectroscopy combined with DFT modeling was used to analyze the electronic structure of the coordinativel

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::246c03e68d189a7b964ef9d8f829b246
https://pubmed.ncbi.nlm.nih.gov/32196900

Zobrazit plný text záznamu

Taking Solution Proton NMR to Its Extreme: Prediction and Detection of a Hydride Resonance in an Intermediate-Spin Iron Complex

Autor: Hubert Wadepohl, Lutz H. Gade, Jonas C. Ott, Markus Enders

Publikováno v: Journal of the American Chemical Society. 140:17413-17417

Guided by DFT based modeling the chemical shift range of a hydride resonance in the proton nuclear magnetic resonance (NMR) spectrum of the intermediate-spin, square planar iron complex tBu(PNP)Fe–H was predicted and detected as a broad resonance a

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::54d487dd85ec522c21e514f53c349c79
https://doi.org/10.1021/jacs.8b11330

Zobrazit plný text záznamu

Synthesis, Characterization, and Reactivity of a High-Spin Iron(II) Hydrido Complex Supported by a PNP Pincer Ligand and Its Application as a Homogenous Catalyst for the Hydrogenation of Alkenes

Autor: Hubert Wadepohl, Clemens K. Blasius, Lutz H. Gade, Jonas C. Ott

Publikováno v: Inorganic Chemistry. 57:3183-3191

This study focused on the synthesis and characterization of a range of low-valent, high-spin iron(II) complexes supported by a carbazole-based PNP pincer-type ligand. The addition of the lithiated ligand (PNP)Li to FeCl

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::fb4c262c415bcf98d0d5b29d8fa1f5f3
https://doi.org/10.1021/acs.inorgchem.7b03227

Zobrazit plný text záznamu

Vyhledávací nástroje:

Upřesnit hledání