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pro vyhledávání: '"John-Paul R. Marrazzo"'
Publikováno v:
JACS Au, Vol 4, Iss 3, Pp 1118-1124 (2024)
Externí odkaz:
https://doaj.org/article/fea0824353fc4a23805378009a79a392
Publikováno v:
The Journal of organic chemistry. 87(1)
A copper iodide-Pyox complex catalyzes the first conjugate addition of diverse sulfur, nitrogen, and carbon nucleophiles to isocyanoalkenes. The anionic addition generates metalated isocyanoalkanes capable of S
Publikováno v:
Organicbiomolecular chemistry. 18(33)
Metalated isocyanides are highly versatile organometallics. Central to the reactivity of metalated isocyanides is the presence of two orthogonally reactive carbons, a highly nucleophilic “carbanion” inductively stabilized by a carbene-like isocya