Zobrazeno 1 - 5
of 5
pro vyhledávání: '"John-Paul F. Cherry"'
Publikováno v:
Canadian Journal of Chemistry. 83:302-307
An alcoholysis strategy has been employed in the synthesis of new oligo- or polymeric trialkoxymolybdenum diazenido complexes [R1NNMo(O-1-Ad)3]x (R1 = Me or C(O)OMe) as well as their mononuclear THF solvates R1NNMo(O-1-Ad)3(THF). Dinitrogen-derived d
Autor:
J. Christopher Thomas, William M. Davis, Luis M. Baraldo, John-Paul F. Cherry, Christopher C. Cummins, Jonas C. Peters, Daniel J. Mindiola
Publikováno v:
Journal of the American Chemical Society. 121:10053-10067
The splitting of dinitrogen (1 atm, THF, 25 °C) by Mo(N[R]Ar)_3 (R = C(CD_3)_2CH_3, Ar = 3,5-C_6H_3Me_2) giving 2 equiv of nitride N⋮Mo(N[R]Ar)3 is found to be accelerated in the presence of sodium amalgam. Careful control of the Mo(N[R]Ar)_3 conc
Autor:
Christopher C. Cummins, John-Paul F. Cherry, Paula L. Diaconescu, Marc J. A. Johnson, Frances H. Stephens
Publikováno v:
Inorganic Chemistry. 40:6860-6862
The syntheses of molybdenum terminal phosphide and dinitrogen complexes supported by N-iso-propylanilide ligands are not as straightforward as those previously reported for the analogous N-tert-butylanilide complexes. To arrive at these synthetic tar
Autor:
John-Paul F. Cherry, Karsten Meyer, Christopher C. Cummins, and Thomas A. Baker, Daniel J. Mindiola
Publikováno v:
Organometallics. 19:1622-1624
Preparation of the terminal nitrido anion -[NNb(N[iPr]Ar)3] and the niobazene trimer {(μ-N)Nb(N[iPr]Ar)2}3 (iPr = CH(CH3)2 or CH(CD3)2, Ar = 3,5-C6H3Me2) entails cooperative splitting of dinitrogen upon reduction of the heterobimetallic paramagnetic
Autor:
Steven P. Nolan, Carl D. Hoff, Kenneth B. Capps, John-Paul F. Cherry, Yi-Chou Tsai, Elena V. Rybak-Akimova, Sergey V. Kryatov, Christopher C. Cummins, Christopher M. Haar, Adam R. Johnson, Luis M. Baraldo
Publikováno v:
Journal of the American Chemical Society. 123(30)
Reaction of Mo(N[R]Ar)(3) (R = (t)Bu or C(CD(3))(2)CH(3)) with N(2)O gives rise exclusively to a 1:1 mixture of nitride NMo(N[R]Ar)(3) and nitrosyl ONMo(N[R]Ar)(3), rather than the known oxo complex OMo(N[R]Ar)(3) and dinitrogen. Solution calorimetry