Zobrazeno 1 - 10
of 11
pro vyhledávání: '"John M. Seakins"'
Publikováno v:
Applied Spectroscopy. 56:909-915
Far-infrared, mid-infrared, and Raman spectroscopy were used to characterize iodine-doped poly(isothianaphthene) (PITN) films and powders. The far-infrared and mid-infrared results show changes from absorption mode to reflective mode as the doping le
Publikováno v:
Synthetic Metals. 128:215-220
Two routes for the synthesis of the low bandgap conductive polymer poly(isothianaphthene), which have significant advantages over previous preparative methods, are examined. The single-step O 2 -induced polymerization of 1,3-dihydroisothianaphthene,
Infrared and Raman spectroscopic studies of the electrochemical oxidative degradation of polypyrrole
Publikováno v:
Synthetic Metals. 95:63-67
Electrochemical oxidative degradation of polypyrrole (PPy), known as overoxidation, in aqueous media has been studied using Raman and FT-IR spectroscopy. Raman spectroscopy was found to be the more sensitive tool to monitor the overoxidation reaction
Publikováno v:
Chemistry of Materials. 9:1878-1886
Electrospray mass spectrometry is a powerful technique for investigating the capping and the functionalization of the surface of a CdS nanocluster, via ligand-exchange reactions. The reactions of the thiophenolate-capped CdS cluster [S4Cd17(SPh)28]2-
Publikováno v:
Chemistry of Materials. 9:967-975
Thiophenolate-capped nanoclusters of cadmium sulfide and the cadmium thiophenolate compounds Cd(SPh)2, [Cd(SPh)4](Me4N)2, [Cd4(SPh)10](Me4N)2, and [Cd4X4(SPh)6](Et4N)2 (X = Cl, Br, I) have been studied by low-frequency FT-IR and Raman spectroscopy. I
Publikováno v:
Journal of Materials Chemistry. 7:1553-1558
Electrospray mass spectra of the metal alkoxides Zr(OEt) 4 , Ti(OEt) 4 , Al(OEt) 3 and Si(OEt) 4 and of Zr(OEt) 4 after reaction with chelating agents have been recorded in dry ethanol. By adding sodium ethoxide to enhance the formation of ions, well
Publikováno v:
Journal of Materials Chemistry. 7:647-651
Oxidation of the surface-capping SPh - ligands of the CdS cluster [S 4 Cd 10 (SPh) 16 ] 4- in solution has been explored as a route to the synthesis of larger, well defined nanocrystals of CdS. Iodine was found to oxidise and remove the SPh - ligands
Publikováno v:
Vibrational Spectroscopy. 9:245-256
Raman and Fourier transform infrared (FT-IR) spectroscopy have been applied to a systematic investigation of the adsorption and decomposition of dichlorodifluoromethane (CCl2F2, CFC-12), fluorotrichloromethane (CCl3F, CFC-11), chlorodifluoromethane (
Autor:
John M. Seakins, Ralph P. Cooney, Graham A. Bowmaker, G. A. Tompsett, K. A. Rodgers, James B. Metson
Publikováno v:
Journal of Raman Spectroscopy. 26:57-62
The Raman microprobe spectra of natural brookite crystals from Switzerland and Brazil and a synthetic brookite powder exhibit a characteristic intense band at 153 cm−1. In contrast, anatase has a band of similar intensity at 144 cm−1 and rutile l
Publikováno v:
Inorganic chemistry. 36(17)
Electrospray mass spectrometry provides a rapid, convenient technique for characterizing and studying the chemistry of anionic metal sulfide thiolate clusters. Negative-ion electrospray mass spectra have been recorded for the thiophenolate-capped clu