Zobrazeno 1 - 10
of 65
pro vyhledávání: '"John M, Pratt"'
Publikováno v:
European Journal of Inorganic Chemistry. 2002:580-583
The equilibria between the five- and six-coordinate species of alkylcobinamide and cobalamin (base-off) have been studied using high-pressure spectroscopic techniques. The addition of a water molecule to the five-coordinate complex is accompanied by
Publikováno v:
Journal of the Chemical Society, Dalton Transactions. :2505-2510
Equilibrium constants K for the substitution of co-ordinated H 2 O in [Fe II (CN) 5 (OH 2 )] 3- by sterically hindered amines (both α and β branching, viz. NH 2 Me–NMe 3 and NH 2 Me–NH 2 Bu t ) and by aniline have been determined in aqueous sol
Autor:
Susan M, Chemaly, Lorna A, Jack, Lesley J, Yellowlees, Pascal L S, Harper, Bauke, Heeg, John M, Pratt
Publikováno v:
Dalton transactions (Cambridge, England : 2003). (14)
Studies of the emission spectra of four Co(III) cobinamides (diaquo-, aquohydroxo-, dihydroxo- and dicyano-) show (1) that the excited states corresponding to the alphabeta and epsilon absorption bands behave like the S(1) and S(2) levels in the non-
Publikováno v:
FEBS Letters. 281:90-92
Equilibrium constants (given as log K/M-1) have been determined at pH 7.4 and 4 degrees C for binding by porcine Intrinsic Factor (B12-binding protein from the gut, specific for the 'cobalamin' series of Co corrinoids) of vitamin B12 or cyanocobalami
Autor:
John M. Pratt, David F.V. Lewis
Publikováno v:
Drug metabolism reviews. 30(4)
(1998). The P450 Catalytic Cycle and Oxygenation Mechanism. Drug Metabolism Reviews: Vol. 30, No. 4, pp. 739-786.
Publikováno v:
Biochemical and biophysical research communications. 178(3)
The possible role of the gamma-glutamyl cycle in the transport of amino acids, using the Caco-2 cell monolayer as an in vitro model of the small intestine, has been investigated. The transport of [2-3H]glycine and [2-3H]glycylglycine through the Caco
Autor:
John M. Pratt, Mohamed S. A. Hamza
Publikováno v:
Journal of the Chemical Society, Dalton Transactions. :3721
Equilibrium constants K have been determined by UV/VIS spectrophotometry for co-ordination of 4-cyanopyridine, pyridine and 4-dimethylaminopyridine (pK 1.9, 5.2 and 9.8 respectively) by the uncharged five-co-ordinate sulfitocobyrinic acid heptamethyl
Autor:
Paul R. Norris, John M. Pratt
Publikováno v:
Journal of the Chemical Society, Dalton Transactions. :3651
Equilibrium constants K for the substitution of co-ordinated H2O in the complex [Fe(CN)5(OH2)]3– by amines have been determined in 0.1 mol dm–3 aqueous acetonitrile solution with I= 0.1 mol dm3–(NaClO4) at 25 °C by UV/VIS spectrophotometry. Th
Autor:
Paul R. Norris, John M. Pratt
Publikováno v:
Journal of the Chemical Society, Dalton Transactions. :3643
Solid Na3[Fe(CN)5(NH3)], which hydrolyses rapidly in solution to the unstable complex [Fe(CN)5(OH2)]3–1, when dissolved in aqueous acetonitrile gave a solution of the much more stable complex [Fe(CN)5(MeCN)]3– with log K 2.6 (25 °C, I= 0.1 mol d
Publikováno v:
Journal of the Chemical Society, Chemical Communications. :2297
Purified P4502B4 (LM2) catalyses the hydroxylation of lauric acid by H2O2 against a background of degradation of the porphyrin ring while iodosylbenzene, which rapidly forms the ferryl FeO3+ derivative, supports neither hydroxylation nor degradation