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pro vyhledávání: '"John Kornfeind"'
Autor:
John Kornfeind, Fraser F. Fleming
Publikováno v:
Tetrahedron Chem, Vol 9, Iss , Pp 100056- (2024)
The protonation, or Lewis Acid complexation, of electrophiles can trigger the sequential insertion of two or more isocyanides resulting in valuable iminonitriles or heterocycles. The number of insertions is controlled by the nature of the alkyl- or a
Externí odkaz:
https://doaj.org/article/7a09947523624fd4bb1143f4f0f8d4bb
Publikováno v:
The Journal of Organic Chemistry. 87:6097-6104
Thermolysis of ω-iodoalkyl-β-siloxyalkenenitriles in DMSO triggers an oxidative cyclization cascade that affords highly oxygenated hydrindanones, decalones, and undecanones. The cyclization cascade is highly unusual on three counts: the cyclization