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pro vyhledávání: '"John Henry Hillhouse"'
Publikováno v:
Canadian Journal of Chemistry. 61:1583-1593
2-Hydroxyethanesulfonyl chloride (1a) is readily made by reaction of an aqueous solution of 2-mercaptoethanol (4a) with chlorine. This is the first clearly proved preparation of a compound which is both an alcohol and a sulfonyl chloride. Reactions o
Publikováno v:
Canadian Journal of Chemistry. 66:1109-1116
The products of reaction of a series of 10 2-substituted ethanesulfonyl chlorides, X—CH2CH2SO2Cl (1), with neopentyl alcohol and pyridine-d5 in nitromethane-d3 showed three reaction pathways depending on the nucleofugality of the substituent, X. Th
Publikováno v:
Canadian Journal of Chemistry. 67:330-334
Ethenesulfonyl chloride (1) reacts with alcohols in the presence of tertiary amines to give a mixture of the alkyl ethenesulfonate (5) and the alkyl betylate (R3′N+CH2CH2SO2OR Cl−). With pyridine and neopentyl alcohol the product composition from
Publikováno v:
Canadian Journal of Chemistry. 63:1-5
Reaction of thiirane 1,1-dioxide (1) with aqueous barium hydroxide gives chiefly barium ethanesulfonate (3) together with some ethylene and barium sulfite, and only a small amount (218O was unsuccessful.
Publikováno v:
Canadian Journal of Chemistry. 62:1977-1995
We present evidence that the reactions of ethenesulfonyl chloride (1) and trans-1-propene-1-sulfonyl chloride (3) with water in the presence of pyridine, trimethylamine, and a number of other tertiary amines proceed primarily by way of an initial vin
Autor:
James F. King, John Henry Hillhouse
Publikováno v:
Journal of the Chemical Society, Chemical Communications. :295
The preparation of 2-hydroxyethanesulphonyl chloride (1), the first example of compound containing both sulphonyl chloride and primary alcohol functions, is described; reaction of (1) with base gives products evidently derived from the sulphene (4) a