Zobrazeno 1 - 10
of 316
pro vyhledávání: '"John H. Holloway"'
Publikováno v:
Molecules, Vol 24, Iss 23, p 4257 (2019)
A halogen-bonded complex formed between methane and chlorine monofluoride has been isolated in the gas phase before the reaction between the components and has been characterised through its rotational spectrum, which is of the symmetric-top type but
Externí odkaz:
https://doaj.org/article/bf293727fd5f49ba9ce492431f7f60b7
Publikováno v:
Molecules
Volume 24
Issue 23
Molecules, Vol 24, Iss 23, p 4257 (2019)
Volume 24
Issue 23
Molecules, Vol 24, Iss 23, p 4257 (2019)
A halogen-bonded complex formed between methane and chlorine monofluoride has been isolated in the gas phase before the reaction between the components and has been characterised through its rotational spectrum, which is of the symmetric-top type but
Autor:
Eric G. Hope, Alan K. Brisdon, Stuart A. Brewer, John Fawcett, P.J. Holliman, John H. Holloway, Russell
Publikováno v:
Zeitschrift für anorganische und allgemeine Chemie. 632:325-329
The direct fluorination of intimately mixed niobium and tantalum powders gives a range of mixed-metal pentafluorides [NbxTa4-xF20] (x = 1 2, 2 3, 3 4) as discreet species isostructural with tantalum pentafluoride (x = 0 1). The crystal structures of
Publikováno v:
Journal of Fluorine Chemistry. 112:185-189
The reaction of [M 3 (CO) 12 ] (M=Ru, Os) with elemental fluorine in anhydrous HF offers a clean, convenient route to [MF(μ-F)(CO) 3 ] 4 . This tetramer reacts with Tris– ortho -hydroxyphenyl phosphine, with the elimination of HF, to give a new, m
Autor:
John H. Holloway, Anthony C. Legon, Stephen A. Cooke, Christopher M. Evans, Zbigniew Kisiel, J. M. A. Thumwood, Gina Cotti
Publikováno v:
Chemistry. 7:2295-2305
Complexes H2O...ClF and H2O...F2 were detected by means of their ground-state rotational spectra in mixtures of water vapour with chlorine monofluoride and difluorine, respectively. A fast-mixing nozzle was used in conjunction with a pulsed-jet, Four
Autor:
Christopher Corcoran, Graham C. Saunders, Eric G. Hope, Alison M. Stuart, John H. Holloway, Steffi Friedrichs, David R. Russell, John Fawcett
Publikováno v:
Journal of the Chemical Society, Dalton Transactions. :161-172
The new fluorine-containing phosphines PPh2(C6H3F2-2,6) I and PPh(C6H3F2-2,6)2 II were synthesized in high yield from C6H3BrF2-2,6 and PPh2Cl or PPhCl2. Phosphines I, II and the previously reported P(C6H3F2-2,6)3 III have been structurally characteri
Publikováno v:
Journal of Molecular Structure. 509:55-65
The ground-state rotational spectra of the isotopomers CH 3 C 14 N⋯ 35 ClF, CH 3 C 14 N⋯ 37 ClF, CD 3 C 14 N⋯ 35 ClF and CH 3 C 15 N⋯ 35 ClF of a symmetric-rotor complex formed by methyl cyanide and chlorine monofluoride have been observed an
Autor:
Graham C. Saunders, Malcolm J. Atherton, Eric G. Hope, David R. Russell, John H. Holloway, John Fawcett
Publikováno v:
Journal of Organometallic Chemistry. 582:163-172
The reaction between [(η 5 -C 5 Me 5 )RhBr(μ-Br)] 2 and the diphosphine, (C 6 F 5 ) 2 PCH 2 CH 2 P(C 6 F 5 ) 2 (dfppe), in benzene proceeded via the intermediate cation [(η 5 -C 5 Me 5 )RhBr(dfppe)] + , which underwent CF and CH bond activat
Autor:
Karl S. Coleman, Howard C.S. Clark, Jane Redding, Eric G. Hope, John H. Holloway, David R. Russell, John Fawcett
Publikováno v:
Polyhedron. 18:1207-1210
A series of [OC-6-33][OsCl2(CO)2L2] (L=phosphine) complexes have been prepared by cleavage of [OsCl(μ-Cl)(CO)3]2 with a variety of phosphines for a comparison of spectroscopic data with those for the related [OC-6-13][OsF2(CO)2L2] (L=phosphine). The
Publikováno v:
Chemical Physics Letters. 298:151-160
Rotational constants, centrifugal distortion constants and all five independent components χaa, χbb−χcc, χab, χac and χbc of the Cl nuclear quadrupole coupling tensor χαβ have been determined for thiophene⋯ 35 ClF and thiophene⋯ 37 ClF