Zobrazeno 1 - 10
of 256
pro vyhledávání: '"John E. McGrady"'
Publikováno v:
Nature Communications, Vol 11, Iss 1, Pp 1-9 (2020)
Many Zintl ions with a single endohedrally encapsulated transition metal ion are known, but relatively few where clusters of two or more metals are present. Here, the authors report the synthesis and characterization of two clusters, [Au8Pb33]6− an
Externí odkaz:
https://doaj.org/article/91520fb1d49d4b2180ab1962f124d94d
Publikováno v:
Inorganics, Vol 10, Iss 6, p 75 (2022)
In this paper, we report the synthesis and structural characterisation of two hetero-metallic clusters, [(CO)3CrSn5Cr(CO)3]4− and [(CO)3MoSn5Mo(CO)3]4−, both of which have a pentagonal bipyramidal core. The structures are similar to that of previ
Externí odkaz:
https://doaj.org/article/672f66d6f43c47feac7e5c92fe633081
Autor:
Robert D. Smyth, Jack N. Blandy, Ziyu Yu, Shuai Liu, Craig V. Topping, Simon J. Cassidy, Catherine F. Smura, Daniel N. Woodruff, Pascal Manuel, Craig L. Bull, Nicholas P. Funnell, Christopher J. Ridley, John E. McGrady, Simon J. Clarke
Publikováno v:
Chemistry of Materials. 34:9503-9516
Autor:
Takafumi Yamamoto, Dihao Zeng, Takateru Kawakami, Vaida Arcisauskaite, Kanami Yata, Midori Amano Patino, Nana Izumo, John E. McGrady, Hiroshi Kageyama, Michael A. Hayward
Publikováno v:
Nature Communications, Vol 8, Iss 1, Pp 1-7 (2017)
Incorporating hydride anions into transition metal oxides can dramatically affect their structural and electronic properties. Here the authors reveal a pressure-induced insulator-to-metal transition in SrVO2H and show that the compressibility of hydr
Externí odkaz:
https://doaj.org/article/89473b4d636c465bbaf94dccf98c4866
Autor:
Bono van IJzendoorn, Saad F. Albawardi, Inigo J. Vitorica-Yrezabal, George F. S. Whitehead, John E. McGrady, Meera Mehta
The first fully characterized boron-functionalized heptaphosphide Zintl cluster, [(BBN)P7]2– ([1]2–), is synthesized by dehydrocoupling [HP7]2–. Dehydrocoupling is a previously unprecedented reaction pathway to functionalize Zintl clusters. [Na
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::08e8d0a19834e8fb2bc0f1296001e98f
https://ora.ox.ac.uk/objects/uuid:382d8eb9-9d13-4345-8fca-d3ff03bb9a0e
https://ora.ox.ac.uk/objects/uuid:382d8eb9-9d13-4345-8fca-d3ff03bb9a0e
We report here the structure of an endohedral plumbaspherene, [Cu4Pb22]4–, the gold analogue of which was previously postulated to be a “missing link” in the growth of larger clusters containing three and four icosahedral subunits. The cluster
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::35aa6b545d1c108ba472fed7a0ca6449
https://ora.ox.ac.uk/objects/uuid:a15c4f02-fba2-4a00-8b73-e13ae56843c2
https://ora.ox.ac.uk/objects/uuid:a15c4f02-fba2-4a00-8b73-e13ae56843c2
Publikováno v:
Chemical Society Reviews, 51 (2), 628–649
Endohedral Zintl clusters—multi-metallic anionic molecules in which a d-block or f-block metal atom is enclosed by p-block (semi)metal atoms—are very topical in contemporary inorganic chemistry. Not only do they provide insight into the embryonic
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::95f10255974e308999920d752b673ca0
https://doi.org/10.1039/d1cs00775k
https://doi.org/10.1039/d1cs00775k
Publikováno v:
Angewandte Chemie International Edition. 62
Group 14 Zintl anions [Ex]q−(E = Si–Pb,x= 4, 5, 9, 10) are synthetically accessible, and their diverse chemical reactivity makes them valuable synthons in the construction of larger nanoclusters with remarkable structures, intriguing patterns of
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::10feccaee0ab06293214881e841fa97b
https://ora.ox.ac.uk/objects/uuid:8f8b85d2-17c2-4f02-aacf-8320113029c9
https://ora.ox.ac.uk/objects/uuid:8f8b85d2-17c2-4f02-aacf-8320113029c9
Publikováno v:
Comprehensive Inorganic Chemistry III ISBN: 9780128231531
Reference Module in Chemistry, Molecular Sciences and Chemical Engineering
Reference Module in Chemistry, Molecular Sciences and Chemical Engineering
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::8887853e972994c41d5bba3a786a2f33
https://doi.org/10.1016/b978-0-12-823144-9.00014-5
https://doi.org/10.1016/b978-0-12-823144-9.00014-5