Zobrazeno 1 - 10
of 38
pro vyhledávání: '"John D. Spence"'
Autor:
Terell E. Keel, Morgan H. Daly, John D. Spence, Alondra J. Cortés, Benjamin F. Gherman, Stephanie A. Valenzuela, Zakery J. E. Tippins
Publikováno v:
The Journal of Organic Chemistry. 82:13297-13312
A combined computational and experimental study was conducted to examine the effect of extended benzannelation orientation on C1–C5 and C1–C6 cyclization of acyclic quinoxalenediynes. Calculations (mPW1PW91/cc-pVTZ//mPW1PW91/6-31G(d,p)) on termin
Autor:
Sergio A. Toscano, John D. Spence, Miranda L. Lackie, Marilyn M. Olmstead, Nicola A. Clayton, Esfir Popova, Michelle A. Farmer
Publikováno v:
Tetrahedron Letters. 55:1569-1572
Sonogashira coupling of buta-1,3-diynylbenzene with ((2-iodophenyl)ethynyl)trimethylsilane and 1,2-diiodobenzene led to the novel enetriyne, 1-ethynyl-2-(phenylbuta-1,3-diynyl)benzene, and enetetrayne, 1,2-bis(phenylbuta-1,3-diynyl)benzene, respectiv
Autor:
Ramiro Fernandez, Andro C. Rios, Megan A. Frost, Sonia Chavez, John D. Spence, Claire M. McCutcheon, Christopher D. Cox, Benjamin F. Gherman
Publikováno v:
The Journal of Organic Chemistry. 77:10329-10339
A series of [b]-fused 6,7-diethynylquinoxaline derivatives have been synthesized through an imine condensation strategy to examine the effect of extended benzannelation on the thermal reactivity of enediynes. Absorption and emission spectra of the hi
Autor:
Heather J. Walker, Trang T. Nguyen, Nadezhda V. Korovina, Michael L. Chang, Benjamin F. Gherman, Ramiro Fernandez, Marilyn M. Olmstead, John D. Spence
Publikováno v:
Organic Letters. 13:3660-3663
A series of naphthalenyl-substituted arenediynes were prepared to examine photochemical reactivity. For naphthalen-1-ylethynyl arenediyne, 350 nm photolysis resulted in a tandem [2 + 2] photocycloaddition to afford cyclobutene adducts. For naphthalen
Publikováno v:
Organic Letters. 11:895-898
Azacalixarenes derived from p-tert-butylphenol are generated by an intramolecular aryl amination strategy as the ring-closing step. The reaction produces the first examples of larger p-tert-butylcalixarenes with regioselective substitution of bridgin
Publikováno v:
Tetrahedron Letters. 48:725-728
Synthetic methodology to prepare porphyrinylethynyl enediynes has been developed. Compared to phenylethynyl derivatives, a bulky porphyrinic substituent on the alkyne significantly increases the thermal barrier toward Bergman cyclization and leads to
Autor:
Melanie A. Muckey, John D. Spence, Gregory M. Ferrence, Timothy D. Lash, Michael J. Hayes, Lisa F. Szczepura
Publikováno v:
The Journal of Organic Chemistry. 67:4860-4874
The "3 + 1" variant of the MacDonald condensation has been shown to be an excellent methodology for synthesizing carbaporphyrins. In particular, 1,3-indenedicarbaldehyde condenses with tripyrranes in the presence of TFA to give, following oxidation w
Publikováno v:
Trauma Case Reports, Vol 43, Iss , Pp 100752- (2023)
Background: Penetrating trauma to the larynx is a rare phenomenon with a high risk of mortality and morbidity due to the density of vital structures in the area (Demetriades et al., 1996). Most commonly, this type of injury is due to a gunshot wound
Externí odkaz:
https://doaj.org/article/fa3579e0cc7f43e390d7b10f0b448a45
Autor:
John D. Spence, Timothy D. Lash
Publikováno v:
The Journal of Organic Chemistry. 65:1530-1539
The Soret band for porphyrins is usually observed in the near-ultraviolet at approximately 400 nm, and few examples of “nonexpanded” porphyrins with this major absorption band at values above 500 n...
Publikováno v:
Synlett. 2000:213-216