Zobrazeno 1 - 10
of 13
pro vyhledávání: '"John Carl Falk"'
Autor:
M. A. Benedetto, John Carl Falk
Publikováno v:
Journal of Applied Polymer Science. 42:659-664
Hydrocarbon solutions of polybutadiene, polyisoprene, and polystyrene may be converted into emulsions. The hydrocarbon solvent may then be removed by distillation. The molecular weight of the polymer controls the particle size of its emulsion. An inc
Autor:
James Van Fleet, John Carl Falk
Publikováno v:
Journal of Applied Polymer Science. 44:1685-1686
SAN-copolyester TPE graft polyblends could be prepared by solution polymerization initiated by peroxide. The resins lose toughness outdoors and in the UV chamber as evidenced by dramatic decreases in short periods of time in ultimate tensile strength
Publikováno v:
Angewandte Makromolekulare Chemie. 57:77-86
Graft polyblends of styrene, acrylonitrile or methyl methacrylate with EPDM rubbers are PVC impact modifiers. Specific compositions in PVC composites have unaged impact strengths similar to PVC composites with commercial ABS, polyacrylate, and chlori
Publikováno v:
Polymer Engineering and Science. 20:763-768
Notch width sensitivity, a serious deficiency of polycarbonate, can be improved by addition of 3–10 percent of specially modified methacrylate-butadiene-styrene (MBS) graft polymers. Blends of these modifiers with polycarbonate are transparent, in
Publikováno v:
Journal of Macromolecular Science: Part A - Chemistry. 7:1669-1676
A new method is described to prepare graft copolymers of polystyrene and polyvinylcyclohexane on polyethylene and poly (ethylene, butene-1). Hydrogenation of the butadiene moieties of graft copolymers of polystyrene on poly-1, 4-butadiene and high vi
Autor:
John Carl Falk, Schlott Richard J
Publikováno v:
Journal of Macromolecular Science: Part A - Chemistry. 7:1663-1668
Rubbers containing a low level of unsaturation such as EPT may be metalated with a chelate made from s-butyllithium and N,N,N′- N′ -tetramethylethylethylenediamine. The lithiated polymers, reacted with styrene, result in polystyrene graft copolym
Publikováno v:
Rubber Chemistry and Technology. 46:1044-1054
Metalation of diene polymers such as poly (butadiene) and poly(isoprene) with sec-butyllithium and tetramethylethylenediamine in cyclohexane at room temperature forms lithiated polydienes. Reaction of the polylithiodienes with styrene or α-methylsty
Autor:
John Carl Falk, Donald A. Tomalia
Publikováno v:
Journal of Heterocyclic Chemistry. 9:891-894
The synthesis of β-substituted ethyl sulfates and their reactions with nucleophilic reagents has been studied. Amines, phenolates, carboxylates, amine oxides, carbanions, and thiophenolates reacted with ethylene sulfate in high yield, with short rea
Publikováno v:
Journal of Macromolecular Science: Part A - Chemistry. 7:1647-1662
Lithiated polydienes were readily prepared by direct metalation of the diene polymers with sec-butyllithium and tetramethylethylenediamine in cyclohexane at room temperature. Reaction of the polylithiodienes with styrene or a-methylstyrene formed gra
Autor:
John Carl Falk
Publikováno v:
Journal of Polymer Science Part A-1: Polymer Chemistry. 9:2617-2623
The selective hydrogenation of poly-1,4-butadiene in the presence of poly-1,4-isoprene is described. Both of these polydienes are hydrogenated more easily than polystyrene. The catalysts which effect these selective hydrogenations are made by the rea