Zobrazeno 1 - 10
of 99
pro vyhledávání: '"John C Cowan"'
Publikováno v:
Journal of the American Oil Chemists' Society. 53:511-517
Soybean and linseed oils were selectively hydroenated with copper-on-silica gel catalyst. The linolenate content of the oils was reduced to diene and monoene with no appreciable increase in saturates. Hydrogenated soybean oils contained 68–76% mono
Publikováno v:
Journal of the American Oil Chemists Society. 51:239-243
Four commercial hydrogenations were carried out on 20,000 1b batches of soybean oil with 0.25, 0.5, and 1% fresh copper-chromite catalyst and 1% used catalyst. Hydrogenations proceeded smoothly at catalyst levels of 0.5 and 1%, but the reaction was s
Publikováno v:
Journal of the American Oil Chemists’ Society. 51:17-21
The anisidine test, a measure of secondary oxidation products in glyceride oils, was applied to a number of soybean salad oils processed from sound and damaged soybeans. A highly significant correlation (−0.68) was found between the anisidine value
Publikováno v:
Journal of the American Oil Chemists Society. 51:509-513
Dried egg mixes prepared commercially with hydrogenated-winterized soybean, corn, or cottonseed oils were evaluated for initial flavor and for flavor storage stability. Quality evaluations were made on products from two processing plants; flavor, col
Publikováno v:
Journal of the American Oil Chemists Society. 53:90-93
1-Nonanol and alkyl 9-hydroxynonanoates were more readily prepared by hydrogenation of the respective isolated aldehydes than by direct hydrogenation of products from reductive ozonolysis of oleate esters. Hydrogenation with nickel catalysts and apro
Publikováno v:
Journal of the American Oil Chemists Society. 51:204-209
9-Aminononanoic acid, 9-aminononanamide, and related compounds derived from soybean oil by reactions, including reductive ozonolysis and reductive amination, were separated on an analytical scale either by gas liquid chromatography of trifluoroacetyl
Publikováno v:
Journal of the American Oil Chemists' Society. 50:132-136
Copper and nickel hydrogenations give a wide distribution of double bonds in the monoene fraction from both reduced soybean and linseed oils. With copper catalysts, high pressure hydrogenation reduces the extent of this double bond distribution when
Publikováno v:
Journal of the American Oil Chemists' Society. 37:37-40
Variables affecting the use of stannic chloride as a catalyst for initiating polymerization of conjugated and nonconjugated soybean vinyl ether were studied. Molecular weight of the polymers increased with an increase in catalyst and a decrease in in
Publikováno v:
Journal of the American Oil Chemists' Society. 45:461-464
Free radical additions of hydrogen sulfide, ethanedithiol, and 1,6-hexanedithiol have been made to methyl oleate and linseed oil with ultraviolet radiation. Reactions were carried out in dichloromethane at −70C and in benzene at 25C. With the dithi
Publikováno v:
Journal of the American Oil Chemists' Society. 38:375-379
A polyaldehydie product called aldehyde oil was prepared by the ozonization of soybean oil, followed by reductive decomposition of the ozonolysis products. Reductive decomposition by chemical means gave 85–90% yields of carbonyl in the aldehyde oil