Zobrazeno 1 - 10 of 14 pro vyhledávání: '"John A. Smegal"'
1
Metalloazine complexes of molybdenum and zirconium
Autor: Georgia M. Arvanitis, John A. Smegal, Ingrid K. Meier, Donna Van Engen, Jeffrey Schwartz, Anthony C. C. Wong
Publikováno v: Organometallics. 8:2717-2723
A series of «metalloazines» of molybdenum and zirconium was prepared. Molybdenum metalloazines are obtained by reaction between diazo compounds and a molybdenum(IV) complex, OMo(DTC) 2 (DTC=a dialkyldithiocarbamate), by oxidative addition. These sp
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::eb86b10e154b28e6d5ce1052d5a417a3
https://doi.org/10.1021/om00113a031
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4
Catalytic replacement of unactivated alkane carbon-hydrogen bonds with carbon-X bonds (X = nitrogen, oxygen, chlorine, bromine, or iodine). Coupling of intermolecular hydrocarbon activation by MnIIITPPX complexes with phase-transfer catalysis
Autor: Timothy J. Henly, Craig L. Hill, John A. Smegal
Publikováno v: The Journal of Organic Chemistry. 48:3277-3281
Les alcanes peuvent etre catalytiquement fonctionnalises pour donner des azido-, chloro-, bromo- et iodo-alcanes et des alcanols en utilisant des systemes avec deux phases liquides dans lesquels la phase organique contient le substrat alcane + le cat
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::89d37d70f943a2c9d7f41421f4520f0e
https://doi.org/10.1021/jo00167a023
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6
Hydrocarbon functionalization by the (iodosylbenzene)manganese(IV) porphyrin complexes from the (tetraphenylporphinato)manganese(III)-iodosylbenzene catalytic hydrocarbon oxidation system. Mechanism and reaction chemistry
Autor: John A. Smegal, Craig L. Hill
Publikováno v: Journal of the American Chemical Society. 105:3515-3521
Die Mn- Porphyrin-Komplexe (I) und (II) reagieren mit prim., sek. und tert. Alkanen in relativ inerten Losungsmitteln wie CH2Cl" Chlor- oder Brombenzol bei 25°C zu funktionalisierten Produkten in guten Ausbeuten.
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::ff03461adc71e2d0e10091b203d1c2f6
https://doi.org/10.1021/ja00349a025
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8
Synthesis, characterization, and reaction chemistry of a bis(iodosylbenzene)metalloporphyrin complex, [PhI(OAc)O]2MnIVTPP. A complex possessing a five-electron oxidation capability
Autor: Craig L. Hill, John A. Smegal
Publikováno v: Journal of the American Chemical Society. 105:2920-2922
The synthesis, characterization, and reaction chemistry of a new type of manganese(IV) complex, (PhI(OAc)O)/sub 2/Mn/sup IV/TPP, which hydroxylates alkanes and epoxidizes olefins is reported. This complex contains both a transition metal (Mn) and a n
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::fa691c816aebefed812124e8fdc0f490
https://doi.org/10.1021/ja00347a079
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9
ChemInform Abstract: HYDROCARBON FUNCTIONALIZATION BY THE (IODOSYLBENZENE)MANGANESE(IV) PORPHYRIN COMPLEXES FROM THE (TETRAPHENYLPORPHINATO)MANGANESE(III)-IODOSYLBENZENE CATALYTIC HYDROCARBON OXIDATION SYSTEM. MECHANISM AND REACTION CHEMISTRY
Autor: Craig L. Hill, John A. Smegal
Publikováno v: Chemischer Informationsdienst. 14
Die Mn- Porphyrin-Komplexe (I) und (II) reagieren mit prim., sek. und tert. Alkanen in relativ inerten Losungsmitteln wie CH2Cl" Chlor- oder Brombenzol bei 25°C zu funktionalisierten Produkten in guten Ausbeuten.
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::04214b79774833ec3a04095b5e943c72
https://doi.org/10.1002/chin.198336321
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