Zobrazeno 1 - 10
of 196
pro vyhledávání: '"John A. Soderquist"'
Autor:
John A. Soderquist
Publikováno v:
ARKIVOC, Vol 2001, Iss 4, Pp 1-4 (2005)
Externí odkaz:
https://doaj.org/article/2b4b9a31a7364148a6866c20af984fd9
Autor:
Jorge Ramos, John A. Soderquist
Publikováno v:
ARKIVOC, Vol 2001, Iss 4, Pp 43-58 (2001)
Externí odkaz:
https://doaj.org/article/e85147d2be524fedb1bd68933cd25c50
Publikováno v:
ARKIVOC, Vol 2001, Iss 4, Pp 12-19 (2001)
Externí odkaz:
https://doaj.org/article/e023dc8521c14f46b72f425f031c0ce0
Autor:
Eyleen Alicea, Eduvigis González, John A. Soderquist, Bakthan Singaram, George W. Kabalka, Lorell Muñoz-Hernández
Publikováno v:
Organic Letters. 17:4368-4371
Asymmetric hydroboration of 1,3-cyclohexadiene with 4R produces the allylborane 5RR as essentially a single diastereomer (i.e., no observable 5RS), and its addition to representative aldehydes provides 9RS (52-75%) with excellent selectivity (94-99%
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ce0e35e01690f2fea54bc851a4483a02
https://doi.org/10.1021/acs.orglett.5b02194
https://doi.org/10.1021/acs.orglett.5b02194
Publikováno v:
Organic letters. 19(2)
Available in either enantiomerically pure form through quantitative Grignard procedures from air-stable crystalline complexes (1, 3), the B-γ-TMS propargylic derivatives of the 10-TMS- (2) and 10-phenyl-9-borabicyclo[3.3.2]decanes (4) provide highly
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e19fc38fc80d6db6abdf6646d5ae7852
https://pubmed.ncbi.nlm.nih.gov/28045535
https://pubmed.ncbi.nlm.nih.gov/28045535
Publikováno v:
Organic Letters. 11:2571-2574
The asymmetric gamma-methoxyallylboration of aldehydes with the configurationally very stable 1 gives nonracemic threo-beta-methoxyhomoallylic alcohols 7 (65-93%) with excellent selectivity (96-99% de, 98-99% ee). The corresponding homoallylic amines
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::119ede1e8d9ad3dcf5bf2ee485524ce0
https://doi.org/10.1021/ol900865y
https://doi.org/10.1021/ol900865y
Publikováno v:
Organometallics. 28:2595-2608
1,1-Diorgano-1-stannacyclopent-3-enes have been synthesized by condensation in THF of magnesium complexes of 1,3-dienes and dichlorodiorganostannanes. 1,1-Dimethyl-, 1,1-di-n-butyl-, 1,1-di-tert-butyl-, and 1,1-diphenyl-1-stannacyclopent-3-enes and 1
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::164f9e4c4bb88bbec96b544af7361412
https://doi.org/10.1021/om800541f
https://doi.org/10.1021/om800541f
Autor:
Buddy Soto-Cairoli, John A. Soderquist
Publikováno v:
Organic Letters. 11:401-404
The allylboration of enantiomerically pure N-triisopropylsilyl-alpha-amino aldehydes (2) with B-allyl-10-trimethylsilyl-9-borabicyclo[3.3.2]decanes (1) proceeds cleanly at -78 degrees C, exhibiting essentially complete reagent control. After an oxida
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::237a370d09b818866a4e70314098ab59
https://doi.org/10.1021/ol802685e
https://doi.org/10.1021/ol802685e
Publikováno v:
Organic Letters. 10:333-336
The disilylation of alpha-amino acids 1 to provide 2 (72-87%) was achieved without racemization. An unprecedented borane-mediated semi-reduction strategy was devised to convert 2 to stable, isolable oxazaborolidines 3 (100%) which were hydrolyzed to
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::db576c12f03dd13a877ea2810ef88f8e
https://doi.org/10.1021/ol7028993
https://doi.org/10.1021/ol7028993
Autor:
José G. Román, John A. Soderquist
Publikováno v:
The Journal of Organic Chemistry. 72:9772-9775
Simple Grignard procedures provide methallylboranes 1a and 1b in enantiomerically pure form from air-stable precursors in 98% and 95% yields, respectively. These reagents add smoothly to aldehydes and methyl ketones, respectively, providing branched
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8150420cf44b3542ad3f438b26d77ee7
https://doi.org/10.1021/jo701633k
https://doi.org/10.1021/jo701633k