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pro vyhledávání: '"Johannes W. Dethlefsen"'
Publikováno v:
Inorganica Chimica Acta. 362:1585-1590
The nitrosyl complex [Cr(dmso) 5 (NO)](PF 6 ) 2 ( 1 ) (dmso = dimethyl sulfoxide) has been prepared by the solvolysis of [Cr(NCCH 3 ) 5 (NO)](PF 6 ) 2 in neat dmso. The optical absorption spectrum of 1 in dmso shows maxima at 734, 567, 450, 413, and
Publikováno v:
Inorganic Chemistry. 48:231-238
Photolysis of the thionitrosyl complex Cr(CH3CN)5(NS)2+ (1) in acetonitrile solution leads to the dissociation of nitrogen monosulfide (NS). In deaerated solution, this reaction is reversible, and flash photolysis studies demonstrate that NS reacts w
Autor:
Anders Døssing, Johannes W. Dethlefsen
Publikováno v:
University of Copenhagen
The green thionitrosyl complex [Cr(OH2)5(NS)]2+ was isolated in solution by the hydrolysis of [Cr(NCCH3)5(NS)]2+. The optical absorption spectra of both compounds are dominated by a band with vibrational progression around 600 nm assigned as a {dyz,z
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::80b9b55761f8ba7181cd00e3189450af
https://curis.ku.dk/portal/en/publications/optical-and-epr-spectra-of-the-thionitrosyl-complex-croh25ns2(24995400-bf9a-11dd-8e02-000ea68e967b).html
https://curis.ku.dk/portal/en/publications/optical-and-epr-spectra-of-the-thionitrosyl-complex-croh25ns2(24995400-bf9a-11dd-8e02-000ea68e967b).html