Zobrazeno 1 - 8
of 8
pro vyhledávání: '"Johannes Rytter Dethlefsen"'
Publikováno v:
ChemCatChem. 10:769-778
A vanadium-catalysed deoxydehydration (DODH) of neat glycerol has been developed. Cheap and readily available ammonium metavanadate (NH4VO3) affords higher yields of allyl alcohol than the well-established catalyst methyltrioxorhenium. A study in whi
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::1e6670b34cf176f83ae87268e793aff2
https://doi.org/10.1002/cctc.201701049
https://doi.org/10.1002/cctc.201701049
Autor:
Daniel Bo Larsen, Ayele Teshome, Johannes Rytter Dethlefsen, Peter Fristrup, Allan Robertson Petersen
Publikováno v:
Chemistry - A European Journal. 22:16621-16631
The molybdate-catalysed transfer hydrodeoxygenation (HDO) of benzyl alcohol to toluene driven by oxidation of the solvent isopropyl alcohol to acetone has been investigated by using a combination of experimental and computational methods. A Hammett s
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2e9cf98ad2b1218d498b276ff54e0f15
https://doi.org/10.1002/chem.201603028
https://doi.org/10.1002/chem.201603028
Publikováno v:
ACS Catalysis. 5:3638-3647
Chemical processes capable of reducing the high oxygen content of biomass-derived polyols are in demand in order to produce renewable substitutes for chemicals of fossil origin. Deoxydehydration (DODH) is an attractive reaction that in a single step
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::f82970f7e59b2fc70e67447b4506f236
https://doi.org/10.1021/acscatal.5b00427
https://doi.org/10.1021/acscatal.5b00427
Publikováno v:
ChemCatChem. 7:1184-1196
The mechanism of the CH3ReO3-catalyzed deoxydehydration of a vicinal diol to an alkene driven by oxidation of a secondary alcohol was investigated by time-resolved, in situ IR spectroscopy and was found to occur in three steps: 1) reduction of the ca
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::dbfb02f683844c47c7ebb2cf67465bf4
https://doi.org/10.1002/cctc.201403012
https://doi.org/10.1002/cctc.201403012
Publikováno v:
Chemistry – A European Journal. 21:3435-3442
The mechanism of the molybdenum-catalyzed de-oxydehydration (DODH) of vicinal diols has been investigat-ed using density functional theory. The proposed catalyticcycle involves condensation of the diol with an Mo VI oxocomplex, oxidative cleavage of
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3fe455cd383279e04b4760a501567713
https://doi.org/10.1002/chem.201405473
https://doi.org/10.1002/chem.201405473
Publikováno v:
ChemInform. 46
Review: recent developments with respect to the substrate scope, alternative reductants, and mechanistic investigations; 62 refs.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::b538407ab6fb10b7497ca996ff9efd67
https://doi.org/10.1002/chin.201519314
https://doi.org/10.1002/chin.201519314
Publikováno v:
ChemSusChem. 7(2)
The commercially available (NH4 )6 Mo7 O24 and other molybdenum compounds are shown to be viable substitutes for the typically employed rhenium compounds in the catalytic deoxydehydration of aliphatic diols into the corresponding alkenes. The transfo
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f02d2e8853694ea721bbd888ff6b38d6
https://pubmed.ncbi.nlm.nih.gov/24399816
https://pubmed.ncbi.nlm.nih.gov/24399816
Publikováno v:
ChemSusChem. 8:909-909
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::9ac5360c53a09f82a5e3d51e286533db
https://doi.org/10.1002/cssc.201500078
https://doi.org/10.1002/cssc.201500078