Zobrazeno 1 - 10
of 13
pro vyhledávání: '"Johannes Freudenreich"'
Publikováno v:
Beilstein Journal of Organic Chemistry, Vol 10, Iss 1, Pp 307-315 (2014)
2-(Dichloromethylidene)-1,1,3,3-tetramethylindane was “hydrolyzed” by solid KOH in DMSO as the solvent at ≥100 °C through an initial chlorine particle transfer to give a Cl,K-carbenoid. This short-lived intermediate disclosed its occurrence th
Externí odkaz:
https://doaj.org/article/e37b7414aacf493aa63349afd21af36e
Publikováno v:
Tetrahedron. 74:7466-7471
Steric shielding of an α,β-unsaturated nitrile R2C = CH–C N by tert-alkyl β-substituents (R) prevented 1,4-additions of organolithiums and showed a remarkably solvent-dependent selectivity of tert-butyllithium (tBuLi): 1,2-addition at C N and α
Autor:
Florian Jäckel, Stefan Böhm, Johannes Freudenreich, Hermann Kügler, Klaus-Gerd Eich, Rike Bartmann, Judith Burkhard, Eva Späth, Jan-Hendrik Herbst
Publikováno v:
Themenzentrierte Interaktion. 32:150-160
Autor:
Johannes Freudenreich
Publikováno v:
Latin American Politics and Society. 58:80-102
Cabinet coalitions are central to the functioning of Latin American presidential systems. However, the reasons for their formation remain unclear. While recent studies suggest that presidents invite parties to the cabinet to facilitate governability
Autor:
Petra Böhrer, Karsten-Olaf Hennig, Bernhard Schubert, Thomas Menke, Rudolf Knorr, Johannes Freudenreich
Publikováno v:
Tetrahedron. 70:2703-2710
Vinylic nucleophilic substitution (SNV) reactions of unactivated, cyclic α,α-dichloroalkenes [(tert-alkyl)2C CCl2] with aryllithiums (RLi) to give (tert-alkyl)2C C(Cl)–R are presented to be carbenoid chain reactions, which involve the unsaturated
Publikováno v:
Beilstein Journal of Organic Chemistry
Beilstein Journal of Organic Chemistry, Vol 10, Iss 1, Pp 307-315 (2014)
Beilstein Journal of Organic Chemistry, Vol 10, Iss 1, Pp 307-315 (2014)
2-(Dichloromethylidene)-1, 1, 3, 3-tetramethylindane was "hydrolyzed" by solid KOH in DMSO as the solvent at >= 100 degrees C through an initial chlorine particle transfer to give a Cl, K-carbenoid. This short-lived intermediate disclosed its occurre
Autor:
Thomas Menke, Claudia Behringer, Petra Böhrer, Claudio Pires, Eva C. Rossmann, Rudolf Knorr, Johannes Freudenreich
Publikováno v:
Journal of the American Chemical Society. 128:14845-14853
The deceptively simple "cross-coupling" reactions Alk(2)C=CA-Cl + RLi --Alk(2)C=CA-R + LiCl (A = H, D, or Cl) occur via an alkylidenecarbenoid chain mechanism in three steps without a transition metal catalyst. In the initiating step 1, the stericall
Autor:
Johannes Freudenreich
Publikováno v:
Politische Vierteljahresschrift. 52:576-578
Publikováno v:
Tetrahedron. 50:5845-5860
Crystalline 2-(lithiomethylene)-1,1,3,3-tetramethylindan (3) forms the etherate 11 as a centrosymmetric dimer with a LiCLiC four-membered ring. The carbanionic terminal of each of the two CC double bonds is tetracoordinated, being bonded at almost eq
Autor:
Bernhard Schubert, Johann Mehlstäubl, Helmut Huber, Petra Böhrer, Therese von Roman, Thi Phung Hoang, David S. Stephenson, Rudolf Knorr, Johannes Freudenreich
Publikováno v:
Magnetic Resonance in Chemistry. 31:557-565
1H and 13C NMR signals were assigned and CH coupling constants (1J, 2J, 3J) determined for a series of α-mono-and α,α-disubstituted (1,1,3,3-tetramethyl-2-indanylidene)methanes with the following α-substituents: (mesityl)2B, n-propyl, phenyl, ter