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pro vyhledávání: '"Johanna C. Viljoen"'
Publikováno v:
J. Chem. Soc., Dalton Trans.. :1041-1045
Several isocyanide–thioether complexes, cis-[M(CNR)(CO)4{S(R1)CH2R2}][M = Cr: R = But, R1R2=(CH2)3S; R = R1= Ph, R2= SPh; R = cyclo -C6H11 or CH2Ph, R1R2=(CH2)3S. M = W : R = But, R1R2=(CH2)3S] were prepared by u.v. irradiation of the corresponding
Publikováno v:
Journal of the Chemical Society, Chemical Communications. :749
Reaction of [Cr(CO)5{[graphic omitted]H2}] with BuLi and CS2(–100°C) followed by alkylation gives the title compound (1), the structure of which has been determined by X-ray crystallography and in which the two preferentially co-ordianated thioket