Zobrazeno 1 - 10
of 10
pro vyhledávání: '"Joern Bruns"'
Autor:
Peter Gross, Joern Bruns, Henning A. Höppe, Matthias Hämmer, Theresa Block, Lukas Heletta, Rainer Pöttgen, Harijs Bariss, Hubert Huppertz, Philip Netzsch
The rare earth borosulfates RE2[B2(SO4)6] with RE = Y, La–Nd, Sm, Eu and Tb–Lu were synthesised under solvothermal conditions starting from the metal chlorides (Pr, Nd, Eu), the metal oxides (Y, La, Ce, Sm, Tb, Dy, Er, Tm, Lu), or the metal powde
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c585964c540b1e1a8614987408c0a27b
https://opus.bibliothek.uni-augsburg.de/opus4/frontdoor/index/index/docId/53074
https://opus.bibliothek.uni-augsburg.de/opus4/frontdoor/index/index/docId/53074
Publikováno v:
Inorganics
Volume 7
Issue 12
Volume 7
Issue 12
Borosulfates are a rapidly expanding class of silicate analogue materials, where the structural diversity is expected to be at least as large as known for silicates. However, borosulfates with cross-linking of the anionic network into two or even thr
Publikováno v:
ChemInform. 47
Tetravalent Pd is detected in coordination by oxoanions via stabilization as a [Pd(S2O7)3]2- complex in which three chelating S2O72- groups surround the metal atom.
Publikováno v:
ChemInform. 46
Publikováno v:
ChemInform. 46
SO3 used in the synthesis of the title compounds is generated by dropping oleum (65% SO3) on P4O10.
Publikováno v:
ChemInform. 46
(NO)4[Pt2(SO4)5] (I) is obtained by the reaction of elemental Pt, oleum (65% SO3), and fuming HNO3 (sealed glass ampoules, 350 °C, 2 d; cooling to 25 °C within 79 h).
Publikováno v:
ChemInform. 45
Direct oxidation of elemental Pt by oleum (65% SO3) in the presence of BaCO3 yields yellow single crystals of Ba[Pt(S2O7)3] (H2SO4)0.5 (H2S2O7)0.5 (sealed glass ampoule, 160 °C).
Publikováno v:
ChemInform. 45
Violet single crystals of Pd(HS2O7)2 are prepared by reaction of elemental Pd and (NO2)OTf in oleum (65% SO3) in a thick-walled glass ampule (90 °C, 24 h).
Publikováno v:
ChemInform. 44
K2[Pd(S4O13)2] is synthesized in nearly quantitative yield by reaction of K2PdCl4 and SO3 (generated from oleum and P4O10) at 120 °C for 2 d.
Publikováno v:
ChemInform. 43
Blue crystals of the title compound are prepared in nearly quantitative yield by the reaction of elemental Pd with SO3 at 120°C (2 d).