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pro vyhledávání: '"Joe M. Davis"'
Autor:
Joe M. Davis
Publikováno v:
Chromatographia. 84:187-197
Approximate equations for the numbers of singlet peaks and total peaks in two-dimensional (2D) separations of randomly distributed component zones predict values of zero as the second-dimension peak capacity 2nc goes to zero. This is the result of de
Autor:
Joe M. Davis
Publikováno v:
Journal of Chromatography A. 1640:461931
The average minimum resolution required for separating adjacent single-component peaks (SCPs) in one-dimensional chromatograms is an important metric in statistical overlap theory (SOT). However, its value changes with changing chromatographic condit
Autor:
Joe M. Davis
Publikováno v:
Journal of chromatography. A. 1588
An equation is proposed for the probability that all mixture constituents are separated, when the density (i.e., average number of eluting constituents per time) and width of single-component peaks (SCPs) vary systematically. The probability Pr that
Autor:
Joe M. Davis, Dwight R. Stoll
Publikováno v:
Journal of chromatography. A. 1537
The probability Pr ( sLC × LC ) that all peaks are separated by a resolution of 1.5 or more in selective comprehensive two-dimensional liquid chromatography (sLC × LC) is computed for simple model systems of 5 to 60 peaks and first-dimension (1D) g
Autor:
Joe M. Davis, Mark R. Schure
Publikováno v:
Journal of chromatography. A. 1523
Orthogonality metrics (OMs) for three and higher dimensional separations are proposed as extensions of previously developed OMs, which were used to evaluate the zone utilization of two-dimensional (2D) separations. These OMs include correlation coeff
Autor:
Joe M. Davis
Publikováno v:
Journal of Chromatography A. 1251:1-9
Equations were proposed recently for computing the distribution of minimum resolution (resolution distribution) of two Gaussian peaks with equal standard deviations, when peak heights in a multi-component separation follow a statistical distribution.
Autor:
Joe M. Davis, Mark R. Schure
Publikováno v:
Journal of Chromatography A. 1218:9297-9306
The chromatographic dimensionality was recently proposed as a measure of retention time spacing based on a power law (fractal) distribution. Using this model, a statistical overlap theory (SOT) for chromatographic peaks is developed that estimates th
Autor:
Joe M. Davis
Publikováno v:
Journal of Chromatography A. 1218:7841-7849
General equations are derived for the distribution of minimum resolution between two chromatographic peaks, when peak heights in a multi-component chromatogram follow a continuous statistical distribution. The derivation draws on published theory by
Publikováno v:
Journal of Chromatography A. 1218:5819-5828
The average value of the multivariate selectivity (SEL) of randomly positioned peaks in a multi-component separation is shown to equal the average fraction of peaks that are singlets, as predicted by statistical-overlap theory (SOT). This equality is
Autor:
Joe M. Davis
Publikováno v:
Talanta. 83:1068-1073
The average numbers of singlet peaks in one-dimensional (1D) and two-dimensional (2D) separations of randomly distributed peaks are predicted by statistical-overlap theory and compared against the effective saturation. The effective saturation is a r