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of 4
pro vyhledávání: '"Jochen Langlotz"'
Autor:
Jochen Langlotz, Helmuth Drevs, Pham Nguyen Chuong, Rudolf Taube, Dirk Steinborn, Norbert Stransky
Publikováno v:
Zeitschrift für Chemie. 28:381-396
Starting from usual principles of redox stability in coordination chemistry and from the donor-acceptor characteristic of organyl ligands the review covers the redox behaviour of transition metals in the coordination with simple carbanions. The main
Publikováno v:
Journal of Organometallic Chemistry. 597:92-104
Zusammenfassung Um den Einflus des Anions X− auf die katalytischen Eigenschaften der kationischen C12-Allylnickel(II)-Komplexe [Ni(C12H19)]X in der stereospezifischen Butadienpolymerisation eingehender zu untersuchen, wurde das Tetrakis(pentafluoro
Publikováno v:
Die Makromolekulare Chemie. 194:1273-1288
The η3, η2, η2-dodeca-2(E), 6(E), 10(Z)-trien-1-yl-nickel(II) complexes [Ni(C12H19)]X (X = SbF6, O3SCF3) were treated in toluene with amorphous aluminium trifluoride (which was prepared from AlEt3 and BF3 · OEt2) in a mole ratio 1 : 10 to 20, for
Autor:
Jochen Langlotz, Rudolf Taube
Publikováno v:
Die Makromolekulare Chemie. 194:705-713
The catalytic properties of η 3 ,η 2 ,η 2 -dodeca-2(E),6(E),10(E)-trien-1-yl-nickel(II) hexafluoroantimonate are investigated in some detail. Under standard conditions the complex catalyses the polymerization of butadiene in toluene at room temper